cobalt(II)(saccharinate)2(hydrazine)2 | 200512-04-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cobalt(II)(saccharinate)2(hydrazine)2
• 英文别名: cobalt(2+);1,1-dioxo-1,2-benzothiazol-2-id-3-one;hydrazine
• CAS: 200512-04-5
• 化学式: C₁₄H₁₆CoN₆O₆S₂
• 分子量: 487.443
• InChiKey: WTIREWOEYBNLKE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸肼 、 coblat(II)(saccharinate)2(H2O)2 在 NaOH 作用下， 以 水 为溶剂， 以30%的产率得到cobalt(II)(saccharinate)2(hydrazine)2
  参考文献：
  名称：

  Synthesis and Characterization of New Mixed-Ligandbis(Hydrazine) andbis(Ethylenediamine) Complexes of Cobalt, Nickel and Copper Saccharinates

  摘要：

  The mixed-ligand saccharin complexes of Co, Ni and Cu with hydrazine and ethylenediamine have been prepared and characterized by elemental analyses, magnetic susceptibility and spectral methods. Hydrazine and ethylenediamine act as bidentate ligands through their N atoms, as expected. The metal ions usually have octahedral geometry with two hydrazine or ethylenediamine molecules and two saccharinate anions in the trans positions. The Cu(II) saccharinate with hydrazine has a bimetallic dimeric structure with Cu-Cu bonds. The Co(III) saccharinate complex with ethylenediamine is also dinuclear, but its dimeric structure is achieved with hydroxo bridges.

  DOI：

  10.1080/00945719708003156