1-Deuteriodec-9-en-1-ol | 1246855-71-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-Deuteriodec-9-en-1-ol
• CAS: 1246855-71-9
• 化学式: C₁₀H₂₀O
• 分子量: 157.26
• InChiKey: QGFSQVPRCWJZQK-MMIHMFRQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-癸烯醛 在 锰 、 2,4,6-collidine deuterochloride 、 重水 作用下， 以 四氢呋喃 为溶剂， 以71%的产率得到1-Deuteriodec-9-en-1-ol
  参考文献：
  名称：

  Mn(0)-Mediated Chemoselective Reduction of Aldehydes. Application to the Synthesis of α-Deuterioalcohols

  摘要：

  A mild simple safe chemoselective reduction of different kinds to the corresponding alcohols mediated by the Mn dust/water system is described. In addition to this, the use of D2O leads to the synthesis of alpha-deuerated alcohols and constitutes an efficient inexpensive alternative for the preparation of these compounds.

  DOI：

  10.1021/jo1015618

文献信息

• Mn(0)-Mediated Chemoselective Reduction of Aldehydes. Application to the Synthesis of α-Deuterioalcohols
  作者：Tania Jiménez、Elisa Barea、J. Enrique Oltra、Juan M. Cuerva、José Justicia

  DOI：10.1021/jo1015618

  日期：2010.10.15

  A mild simple safe chemoselective reduction of different kinds to the corresponding alcohols mediated by the Mn dust/water system is described. In addition to this, the use of D2O leads to the synthesis of alpha-deuerated alcohols and constitutes an efficient inexpensive alternative for the preparation of these compounds.