bis(4,4'-dimethyl-2,2'-bipyridine-N,N')(4,5-dihydroxy-1,2-benzoquinonato-O,O')nickel(II) monohydrate | 175860-26-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(4,4'-dimethyl-2,2'-bipyridine-N,N')(4,5-dihydroxy-1,2-benzoquinonato-O,O')nickel(II) monohydrate
• CAS: 175860-26-1
• 化学式: C₃₀H₂₆N₄NiO₄*H₂O
• 分子量: 583.266
• InChiKey: CEZAYLRWLSJFSR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(4,4'-dimethyl-2,2'-bipyridine-N,N')nickel(II) dichloride 、 4,5-dihydroxy-1,2-benzoquinone 、 manganese(ll) chloride 在 metasilica gel 作用下， 以 not given 为溶剂， 生成 bis(4,4'-dimethyl-2,2'-bipyridine-N,N')(4,5-dihydroxy-1,2-benzoquinonato-O,O')nickel(II) monohydrate
  参考文献：
  名称：

  Two 2,5-Dihydroxy-1,4-benzoquinonate-O,O'-Containing Mononuclear Complexes: [Cu(C6H2O4)(C8H6N4)(H2O)].5H2O and [Ni(C6H2O4)(C12H12N2)2].H2O (C8H6N4 = 2,2'-Bipyrimidine, C12H12N2 = 4,4'-Dimethyl-2,2'-bipyridine)

  摘要：

  The crystal structures of aqua(2,2'-bipyrimidine-N,N')(4,5-dihydroxy-1,2-benzoquinonato-O,O')copper-(II) pentahydrate, [CU(C6H2O4)(C8H6N4)(H2O)].5H(2)O, containing five-coordinate copper(II) with slightly distorted square-pyramidal geometry, and bis(4,4'-dimethyl-2,2'-bipyridine-N,N')(4,5-dihydroxy-1,2-benzoquinonato-O,O')nickel(II) monohydrate, [Ni(C6H2O4)-(C12H12N2)(2)].H2O, comprising six-coordinate nickel(II) with distorted octahedral geometry, are reported. In both complexes, the dianion of 2,5-dihydroxy-1,4-benzoquinone occurs in the bidentate o-benzoquinone form which chelates through the 1,2 O atoms.

  DOI：

  10.1107/s0108270195010298