(2-FPhCH2)(2-pyridinecarboxylate)2Sn(2-FPhCOO) | 906454-20-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2-FPhCH2)(2-pyridinecarboxylate)2Sn(2-FPhCOO)
• CAS: 906454-20-4
• 化学式: C₂₆H₁₈F₂N₂O₆Sn
• 分子量: 611.146
• InChiKey: XXELMTLYSBIICJ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-吡啶甲酸 、 (2-FPhCH2)2SnO 、 氧气 在 silver sulfite CH₃COONa 作用下， 以 苯 为溶剂， 以35%的产率得到(2-FPhCH2)(2-pyridinecarboxylate)2Sn(2-FPhCOO)
  参考文献：
  名称：

  Catalytic oxidation of diorganotin(IV) carboxylates to mixed-ligand monoalkyltin(IV) carboxylates by Ag+ and structure characterization of the mixed-ligand monoalkyltin(IV) 2-pyridinecarboxylate (2-ClPhCH2)Sn(2-ClPhCO2)(O2CC5H4N-2)2

  摘要：

  The complexes of the type (ArCH2)(2)SnO were catalytic-oxygenated by Ag+ and yielded mixed-ligand organotin(IV) complexes (ArCH2)(2-C5H4NCO2)(2)(ArCOO)tin(IV) (Ar = C6H5 (1), 2-ClC6H4 (2), 2-CNC6H4 (3), 4-ClC6H4 (4), 4-CNC6H4 (5), 2-FC6H4 (6)). The complexes 1-6 are characterized by elemental analyses, IR and NMR (H-1, C-13, Sn-119) spectroscopies. Single X-ray crystal structure analysis has been determined, which reveals that the center tin atom of complex 2 is seven-coordinated geometry. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.02.037