tetraphenyleno[1,16-bcd:8,9-b'c'd']difuran | 1613140-40-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: tetraphenyleno[1,16-bcd:8,9-b'c'd']difuran
• CAS: 1613140-40-1
• 化学式: C₂₄H₁₂O₂
• 分子量: 332.358
• InChiKey: IPECSECVCRBJCO-RFIZXXDFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.23
• 重原子数：
  26.0
• 可旋转键数：
  0.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.28
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  tetraphenyleno[1,16-bcd:8,9-b'c'd']difuran 在 溴 、 溶剂黄146 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以19.6 g的产率得到
  参考文献：
  名称：

  다환 화합물 및 이를 포함하는 유기 발광 소자

  摘要：

  这份规范提供了被表示为化学式1的化合物以及包含它的有机发光器件。

  公开号：

  KR20190085878A
• 作为产物：
  描述：

  (R,R)-1,8,9,16-tetra(trifluoromethanesulfonyloxy)tetraphenylene 在 potassium phosphate 、 四(三苯基膦)钯 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以68%的产率得到tetraphenyleno[1,16-bcd:8,9-b'c'd']difuran
  参考文献：
  名称：

  Heteroatom-Bridged Tetraphenylenes: Synthesis, Structures, and Properties

  摘要：

  Novel oxygen-, nitrogen-, sulfur-, and selenium-bridged tetraphenylenes were prepared from known tetraphenylene derivatives. Structures of these compounds were unambiguously confirmed by X-ray crystallographic analyses. Photophysical and electrochemical investigations of these heteroatom-bridged tetraphenylenes suggested their potential applications as electronic materials.

  DOI：

  10.1021/ol501267z

文献信息

• ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：NANJING TOPTO MATERIALS CO.,LTD.

  公开号：US20180105534A1

  公开（公告）日：2018-04-19

  The present invention provides an organic electroluminescent compound and an organic electroluminescent device using the organic electroluminescent compound, the compound has the following structural formula: wherein R 1 , R 2 and R 4 are, each independently, selected from a group consisting of a hydrogen atom, a C1-C20 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolinyl group and a triazinyl group; R 3 is selected from a group consisting of hydrogen atom, a C1-C10 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolinyl group and a triazinyl group.

  本发明提供了一种有机电致发光化合物及使用该有机电致发光化合物的有机电致发光器件，该化合物具有如下结构式： 式中，R1、R2和R4分别为，每个独立地，选自包括氢原子、C1-C20的直链或支链烷基团、取代或未取代的N-(苯甲基)亚胺基团、苯基、苯胺、二苯胺、苯基吡啶基胺、双吡啶基胺、苯基萘胺、双萘胺、苯基菲胺、双菲胺、苯基蒽胺、双蒽胺、菲啶、联苯、吡啶基团、嘧啶基团、喹啉基团和三嗪基团在内的组；R3选自包括氢原子、C1-C10的直链或支链烷基团、取代或未取代的N-(苯甲基)亚胺基团、苯基、苯胺、二苯胺、苯基吡啶基胺、双吡啶基胺、苯基萘胺、双萘胺、苯基菲胺、双菲胺、苯基蒽胺、双蒽胺、菲啶、联苯、吡啶基团、嘧啶基团、喹啉基团和三嗪基团在内的组。