trans-bis(1,2-bis(dipropylphosphino)ethane)bisazidoiron(II) | 170126-56-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trans-bis(1,2-bis(dipropylphosphino)ethane)bisazidoiron(II)
• CAS: 170126-56-4
• 化学式: C₂₈H₆₄FeN₆P₄
• 分子量: 664.598
• InChiKey: VRNITGBZVTUMNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Fe(1,2-bis(dipropylphosphino)ethane)2Cl2 、 sodium azide 以 甲醇 为溶剂， 以54%的产率得到trans-bis(1,2-bis(dipropylphosphino)ethane)bisazidoiron(II)
  参考文献：
  名称：

  Synthesis and reactions of azido complexes of iron

  摘要：

  Sodium azide reacts with FeH2(dmpe)(2) (1a) dmpe = 1,2-bis(dimethylphosphino)ethane in methanol solution to form FeH(N-3)(dmpe)(2) (3a) and, finally, Fe(N-3)(2)(dmpe)(2) (2a). The bis(azide) complex may also be generated from FeCl2(dmpe)(2) (4a) by a ligand exchange reaction. The azide ligand is easily replaced by terminal alkynes to form bisacetyl iron complexes. The X-ray crystal structure of Fe(N-3)(2)(dmpe)(2) (2a) shows that the azide groups are mutually trans and that the N-N-N groups are essentially linear and tilted by approximately 132 degrees with respect to the plane containing the Fe and the four P atoms.

  DOI：

  10.1016/0277-5387(95)00043-r