[Cu(II)(2,5-bis(pyrazol-1-yl)-1,4-dihydroxybenzene)]n | 403822-33-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Cu(II)(2,5-bis(pyrazol-1-yl)-1,4-dihydroxybenzene)]n
• CAS: 403822-33-3
• 化学式: C₁₂H₈CuN₄O₂
• 分子量: 303.767
• InChiKey: BMSFTAHNXLYPCL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,5-bis(pyrazol-1'-yl)-1,4-dihydroxybenzene 、 copper(ll) bromide 以 二氯甲烷 、 氨 为溶剂， 以95%的产率得到[Cu(II)(2,5-bis(pyrazol-1-yl)-1,4-dihydroxybenzene)]n
  参考文献：
  名称：

  One-Dimensional Spin Chains from CuII Ions and 2,5-Bis(pyrazol-1-yl)-1,4-dihydroxybenzene

  摘要：

  The purple colored coordination polymer [1 Cu](n) was obtained from 2,5-bis(pyrazol-1-yl)-1,4-dihydroxybenzene and CuBr2 in aqueous ammonia. The crystal structure of [1 Cu](n) was determined from high resolution X-ray powder diffraction data using the method of simulated annealing. In the solid state, [1 Cu](n) features largely independent linear chains, all of them being oriented parallel to the c-axis of the crystal. The Cu ions are coordinated in a square-planar fashion by two nitrogen atoms and two anionic oxygen donors. Magnetic susceptibility and magnetization measurements indicate the Cu ions in [1 Cu](n) to be antiferromagnetically coupled with a coupling constant of about 20 K.

  DOI：

  10.1002/1521-3749(200201)628:1<310::aid-zaac310>3.0.co;2-3