(difluoromethylene)cyclopropene | 67948-89-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (difluoromethylene)cyclopropene
• 英文别名: Difluoromethylene-cyclopropene；3-(difluoromethylidene)cyclopropene
• CAS: 67948-89-4
• 化学式: C₄H₂F₂
• 分子量: 88.0567
• InChiKey: GXNYNLYHRJRIQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (difluoromethylene)cyclopropene 以 various solvent(s) 为溶剂， 生成 1,1-difluorobut-1-ene-3-yne
  参考文献：
  名称：

  Evidence for the Non-Concerted Addition of Difluorovinylidene to Acetylenes

  摘要：

  DOI：

  10.1002/(sici)1521-3765(19981102)4:11<2360::aid-chem2360>3.0.co;2-y
• 作为产物：
  描述：

  poly(vinylidene fluoride) 、 乙炔 以 solid matrix 为溶剂， 生成 (difluoromethylene)cyclopropene
  参考文献：
  名称：

  Reactions of Difluorovinylidene—A Super-Electrophilic Carbene

  摘要：

  Difluorovinylidene is the only vinylidene that could be isolated in low temperature matrices, so far, Its unusual reactivity is governed by its extreme electrophilicity and electron affinity, Thus, it not only adds CO and N without difficulties, but also inserts into CH4 and even H-2 at temperatures below 40 K. The reaction of F2C=C: with FC=CF clearly reveals that the formation of methylenecyclopropene proceeds in a stepwise reaction, The most striking example for the electrophilicity of F2C=C: is the thermal reaction with Xe to give a charge-transfer complex with a characteristic IR spectrum.

  DOI：

  10.1002/(sici)1521-3765(19990104)5:1<24::aid-chem24>3.0.co;2-z