(2S,3R,4S,5R,6R)-6-((methacryloyloxy)methyl)-5-(((2S,3R,4S,5R,6R)-3,4,5-tris(methacryloyloxy)-6-((methacryloyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2,3,4-triyl tris(2-methylacrylate) | 1198418-14-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3R,4S,5R,6R)-6-((methacryloyloxy)methyl)-5-(((2S,3R,4S,5R,6R)-3,4,5-tris(methacryloyloxy)-6-((methacryloyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2,3,4-triyl tris(2-methylacrylate)
• CAS: 1198418-14-2
• 化学式: C₄₄H₅₄O₁₉
• 分子量: 886.901
• InChiKey: KCQCEFXLUGLPCG-IRPBIXCPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.62
• 重原子数：
  63.0
• 可旋转键数：
  20.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  238.09
• 氢给体数：
  0.0
• 氢受体数：
  19.0

反应信息

• 作为反应物：
  描述：

  (2S,3R,4S,5R,6R)-6-((methacryloyloxy)methyl)-5-(((2S,3R,4S,5R,6R)-3,4,5-tris(methacryloyloxy)-6-((methacryloyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2,3,4-triyl tris(2-methylacrylate) 、 12-(benzyloxy)dodecan-1-ol 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 以40%的产率得到C₅₉H₈₀O₁₉
  参考文献：
  名称：

  Permethacrylated carbohydrates: synthesis and reactivity in glycosidation reaction

  摘要：

  The synthesis of various permethacrylated mono- and disaccharides in acceptable yields is reported. The reactivity of these unusual polymerizable compounds has been investigated in diverse glycosidation reaction conditions. New original polymerizable donor sugars have been prepared successfully in good to excellent yields. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.08.083
• 作为产物：
  描述：

  甲基丙烯酸酐 、 D-纤维二糖 在 sodium acetate 作用下， 以35%的产率得到(2S,3R,4S,5R,6R)-6-((methacryloyloxy)methyl)-5-(((2S,3R,4S,5R,6R)-3,4,5-tris(methacryloyloxy)-6-((methacryloyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2,3,4-triyl tris(2-methylacrylate)
  参考文献：
  名称：

  Permethacrylated carbohydrates: synthesis and reactivity in glycosidation reaction

  摘要：

  The synthesis of various permethacrylated mono- and disaccharides in acceptable yields is reported. The reactivity of these unusual polymerizable compounds has been investigated in diverse glycosidation reaction conditions. New original polymerizable donor sugars have been prepared successfully in good to excellent yields. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.08.083