[(triphenylphosphine)(imidazoline-2(1,3H)-thione)2-copper(I)](perchlorate) | 242486-18-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(triphenylphosphine)(imidazoline-2(1,3H)-thione)2-copper(I)](perchlorate)
• 英文别名: copper(1+);1,3-dihydroimidazole-2-thione;triphenylphosphane;perchlorate
• CAS: 242486-18-6
• 化学式: C₂₄H₂₃CuN₄PS₂*ClO₄
• 分子量: 625.576
• InChiKey: XLUVWOSJHRKUGG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.83
• 重原子数：
  37
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  187
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-巯基咪唑 、 perchloratetetrakis(triphenylphosphine)copper(I) 以 乙醚 为溶剂， 以48%的产率得到[(triphenylphosphine)(imidazoline-2(1,3H)-thione)2-copper(I)](perchlorate)
  参考文献：
  名称：

  Synthesis and characterization of derivatives of copper(I) with N- and S-donor ligands

  摘要：

  New copper(I) complexes of the type [(PBz(3))L3Cu]X, (PBz(3))L2CuX, [(PBz(3))(2)L2Cu]X, [(PBz(3))(3)LCu]X (L=monodentate N-donor imidazole- or pyrazole-type ligand, Bz=benzyl, X=NO3 or ClO4), (PBz(3))(y)(N-N)(x)CuNO3 (N-N=bis(pyrazol-1-yl)methane, x=y=1; N-N=bis(1,2,4-triazol-1-yl)methane, x=y=2), (PPh3)L-2'CuX, (PPh3)(2)L'CuX, [(PPh3)L-3'Cu]X and (PPh3)L'CuX, (L'=monodentate S-donor 1-methyl-imidazoline-2(3H)-thione or imidazoline-2(1,3H)-thione) were obtained from the reaction of (PR3)(n)CuX with the appropriate N- or S-donor ligand. Reaction between [(PPh3)(n)Cu(L)(m)]X with PBz(3) often resulted in the formation of new [(PBz(3))(z)Lm-1Cu]X (z=n or n+1) complexes upon displacement of one molecule of L and two or three molecules of PPh3, whereas reaction of [(N-N)(2)Cu]ClO4 with PBz(3) and 1,10-phenanthroline (Phen) yielded [(PBz(3))(2)CuClO4] and [(Phen)(2)Cu]ClO4, respectively, upon displacement of both molecules of bidentate chelating ligands. No reaction occurred between (PPh3)L-2'CuX, (PPh3)(2)L'CuX or [(PPh3)L-3'Cu]X and PBz(3). All the derivatives obtained were characterized by IR spectroscopy, H-1 NMR, and conductance studies, and in some cases also by molecular weight measurements. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00089-3