6-[4-[2-[12-(4,5-diphenyl-1H-imidazol-2-yl)-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-4-(4-methoxyphenyl)-1H-imidazol-5-yl]phenoxy]hexyl 2-methylprop-2-enoate | 1220516-16-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 6-[4-[2-[12-(4,5-diphenyl-1H-imidazol-2-yl)-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-4-(4-methoxyphenyl)-1H-imidazol-5-yl]phenoxy]hexyl 2-methylprop-2-enoate
• CAS: 1220516-16-4
• 化学式: C₅₇H₅₄N₄O₄
• 分子量: 859.08
• InChiKey: GSYFKIPLHYDZOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  65
• 可旋转键数：
  17
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  6-[4-[2-[12-(4,5-diphenyl-1H-imidazol-2-yl)-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-4-(4-methoxyphenyl)-1H-imidazol-5-yl]phenoxy]hexyl 2-methylprop-2-enoate 在 potassium hydroxide 、 potassium hexacyanoferrate(III) 作用下， 以 水 、 苯 为溶剂， 反应 0.5h， 以80%的产率得到6-(4-(1'-(4-methoxyphenyl)-4,5-diphenyl-8',9'-dihydrospiro[imidazole-2,14'-[5,12]ethanodibenzo[c,g]imidazo[1,2-a]azonin]-2'-yl)phenoxy)hexyl methacrylate
  参考文献：
  名称：

  Fast Photochromic Polymers Carrying [2.2]Paracyclophane-Bridged Imidazole Dimer

  摘要：

  The synthesis and photochromic behavior of the fast photochromic polymers carrying [2.2]paracyclophane-bridged imidazole dimer are demonstrated. A significant feature of this synthetic strategy is that we can modify the photochromic properties such as coloration/decoloration rate, coloring, and photosensitivity via the stepwise synthetic approach of the imidazole dimer system. Notably, the photochromic behavior of the polymers is not affected by the environment around the photochromes and copolymerization with other monomers in both solution and film, which cannot be realized in any other conventional photochromic systems. The comparable photochromic behavior of the homopolymers and copolymers in solution and film indicates that the photochromic unit is independent from the local environment, which allows effective molecular design of the photochromic monomer unit to accomplish desired photochromic properties of the polymer.

  DOI：

  10.1021/ma100197z
• 作为产物：
  描述：

  1-[4-(6-Hydroxyhexoxy)phenyl]-2-(4-methoxyphenyl)ethane-1,2-dione 在 ammonium acetate 、 溶剂黄146 、 4-甲氧基苯酚 、 三乙胺 、 对苯二酚 作用下， 以 二氯甲烷 为溶剂， 反应 96.0h， 生成 6-[4-[2-[12-(4,5-diphenyl-1H-imidazol-2-yl)-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-4-(4-methoxyphenyl)-1H-imidazol-5-yl]phenoxy]hexyl 2-methylprop-2-enoate
  参考文献：
  名称：

  Fast Photochromic Polymers Carrying [2.2]Paracyclophane-Bridged Imidazole Dimer

  摘要：

  The synthesis and photochromic behavior of the fast photochromic polymers carrying [2.2]paracyclophane-bridged imidazole dimer are demonstrated. A significant feature of this synthetic strategy is that we can modify the photochromic properties such as coloration/decoloration rate, coloring, and photosensitivity via the stepwise synthetic approach of the imidazole dimer system. Notably, the photochromic behavior of the polymers is not affected by the environment around the photochromes and copolymerization with other monomers in both solution and film, which cannot be realized in any other conventional photochromic systems. The comparable photochromic behavior of the homopolymers and copolymers in solution and film indicates that the photochromic unit is independent from the local environment, which allows effective molecular design of the photochromic monomer unit to accomplish desired photochromic properties of the polymer.

  DOI：

  10.1021/ma100197z