copper;(3-amino-2,2-dimethylpropyl)-[2-(3-amino-2,2-dimethylpropyl)azanidyl-2-oxoacetyl]azanide;iron(2+);propane-1,3-diamine;sulfate | 242486-46-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: copper;(3-amino-2,2-dimethylpropyl)-[2-(3-amino-2,2-dimethylpropyl)azanidyl-2-oxoacetyl]azanide;iron(2+);propane-1,3-diamine;sulfate
• CAS: 242486-46-0
• 化学式: C₁₈H₄₄CuFeN₈O₂*O₄S
• 分子量: 620.056
• InChiKey: KCENPLGLFDGUDS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ferrous(II) sulfate heptahydrate 、 Cu(N,N'-bis(3-amino-2,2'-dimethylpropyl)oxamido) 、 1,3-丙二胺 以 甲醇 为溶剂， 以81%的产率得到copper;(3-amino-2,2-dimethylpropyl)-[2-(3-amino-2,2-dimethylpropyl)azanidyl-2-oxoacetyl]azanide;iron(2+);propane-1,3-diamine;sulfate
  参考文献：
  名称：

  Synthesis, Characterization and Magnetic Properties of μ-Oxamido Heterodinuclear Copper(II)-Iron(II) Complexes

  摘要：

  Five new mu-oxamido heterodinuclear copper(II)-iron(II) complexes of the formula [Cu(Me(2)oxpn)Fe(L)(2)]SO4, where Me(2)oxpn denotes N,N'-bis(3-amino-2,2-dimethylpropyl)oxamido dianion and L represents diaminoethane ten), 1,3-diaminopropane (pn), 1,2-diaminopropane (ap), 2,9-dimethyl-1,10-phenanthroline (Me(2)phen) and 4,4'-dimethyl-2,2'-bipyridine (Me(2)bpy), have been synthesized and characterized by elemental analyses, spectroscopic studies, magnetic moments (at room temperature) and molar conductivity measurements. It is proposed that these complexes have extended oxamido-bridged structures consisting of planar copper(II) and octahedral iron(II) ions. The [Cu(Me(2)oxpn)Fe(en)(2)]SO4 (1) and [Cu(Me(2)oxpn)Fe(pn)(2)]SO4 (2) complexes have been further characterized by variable temperature magnetic susceptibility (4.2-300 K). The observed data were least-squares fitted to the susceptibility equation derived from the spin Hamiltonian including single-ion zero-field interaction for the iron(II) ion, (H) over cap = -2J (S) over cap(1) . (S) over cap(2) - D (S) over cap(Z1)(2), giving the exchange integrals J = -18.8 cm(-1) for (1) and J = -20.9 cm(-1) for (2). These results indicate that the spin-coupling between the adjacent copper(II) and iron(II) ions through the oxamido-bridge in both complexes (1) and (2) is antiferromagnetic.

  DOI：

  10.1080/00945719909349527