| 1438430-42-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1438430-42-2
• 化学式: C₁₇H₂₄N₂O₂P₂
• 分子量: 350.337
• InChiKey: AVHCSURXSBLMPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.46
• 重原子数：
  23.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  66.24
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 生成
  参考文献：
  名称：

  Synthesis of Bis(2-Pyridylphosphino)Alkanes in Superbasic Medium and Their Hydroxymethyl Derivatives

  摘要：

  Novel P-H-diphosphinoalkanes with pyridyl substituents at the phosphorus atoms have been obtained in good or moderate yields by the interaction of primary 2-pyridyl-phosphine with dichloroalkanes in superbasic medium. The formation of novel 1-(2-pyridyl)-1-phosphacyclopentane together with bis(2-pyridylphosphino)butane was observed as the result of the interaction of 2-pyridylphosphine and 1,4-dichlorobutane under the same reaction conditions. The reaction of the bis(2-pyridylphosphino)alkanes thus obtained with formaldehyde leads to the formation of the corresponding hydroxymethyl derivatives.

  DOI：

  10.1080/10426507.2012.729118