3-甲基-1-苯基庚烷-1-酮 | 57001-88-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 3-甲基-1-苯基庚烷-1-酮
• 英文名称: methyl-3 phenyl-1 heptanone-1
• 英文别名: 2-methylhexyl phenyl ketone；1-Phenyl-3-methyl-1-heptanon；1-Heptanone, 3-methyl-1-phenyl-；3-methyl-1-phenylheptan-1-one
• CAS: 57001-88-4
• 化学式: C₁₄H₂₀O
• 分子量: 204.312
• InChiKey: MWQYDLMEBJCMME-UHFFFAOYSA-N

物化性质

• 沸点：
  289.1±9.0 °C(Predicted)
• 密度：
  0.927±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-azidostyrene 生成 3-甲基-1-苯基庚烷-1-酮
  参考文献：
  名称：

  SUZUKI A.; TABATA M.; UEDA M., TETRAHEDRON LETT. , 1975, NO 26, 2195-2198

  摘要：

  DOI：

文献信息

• El-Jazouli, Mustapha; Lage, Nadia; Masson, Serge, Bulletin de la Societe Chimique de France, 1988, # 5, p. 883 - 888
  作者：El-Jazouli, Mustapha、Lage, Nadia、Masson, Serge、Thuillier, Andre

  DOI：——

  日期：——
• A chiral (alkoxy)methyl-substituted silicon group as an auxiliary for the stereoselective cuprate addition to α,β-unsaturated ketones: synthesis of (−)-(R)-phenyl 2-phenylpropyl ketone
  作者：Svestoslav Bratovanov、Stefan Bienz

  DOI：10.1016/s0957-4166(97)00134-1

  日期：1997.5

  The [(benzyloxy)methyl](tert-butyl)methylsilyl group was used as the chiral auxiliary to effect highly diastereoselective conjugate additions of organocuprates to enones. Thus, reaction of several R2CuLi with alpha-silylated alpha,beta-unsaturated ketones afforded the respective addition products with pi-face selectivities of up to 99%. Starting with an optically active substrate, enantiomerically enriched (-)-(R)-phenyl 2-phenylpropyl ketone was prepared with virtually no loss of chiral information in a reaction sequence involving cuprate addition, hydrolysis, and removal of the silicon group. (C) 1997 Elsevier Science Ltd.
• Jazouli, Mustapha El; Masson, Serge; Thuillier, Andre, Journal of the Chemical Society. Chemical communications, 1985, # 22, p. 1598 - 1599
  作者：Jazouli, Mustapha El、Masson, Serge、Thuillier, Andre

  DOI：——

  日期：——
• EL-JAZOULI, MUSTAPHA;LAGE, NADIA;MASSON, SERGE;THUILLIER, ANDRE, BULL. SOC. CHIM. FR. PT 1,(1988) NEPT. - OCT., C. 883-888
  作者：EL-JAZOULI, MUSTAPHA、LAGE, NADIA、MASSON, SERGE、THUILLIER, ANDRE

  DOI：——

  日期：——