diethyl 9,10-anthracenedipropionate | 132056-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: diethyl 9,10-anthracenedipropionate
• 英文别名: ethyl 3-[10-(3-ethoxy-3-oxopropyl)anthracen-9-yl]propanoate
• CAS: 132056-51-0
• 化学式: C₂₄H₂₆O₄
• 分子量: 378.468
• InChiKey: IYJVRZYWXTWSLF-UHFFFAOYSA-N

物化性质

• 沸点：
  530.4±30.0 °C(Predicted)
• 密度：
  1.149±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  28
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diethyl 9,10-anthracenedipropionate 在 lithium hydroxide monohydrate 作用下， 以 四氢呋喃 、 水 为溶剂， 以47 %的产率得到蒽-9，10-二丙酸
  参考文献：
  名称：

  CN116514633

  摘要：

  公开号：
• 作为产物：
  描述：

  diethyl 9,10-anthracenediacrylate 在 palladium diacetate 、 potassium formate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 29.33h， 以95%的产率得到diethyl 9,10-anthracenedipropionate
  参考文献：
  名称：

  一种9,10-二(N-(2,3-二羟丙基)丙酰胺基)蒽的制备方法

  摘要：

  本发明提供了一种9,10‑二(N‑(2,3‑二羟丙基)丙酰胺基)蒽(DHPA)的制备方法，涉及化学合成技术领域。包括以下步骤：将9,10‑二溴蒽、丙烯酸乙酯、第一钯催化剂、配体、碱和第一有机溶剂混合进行Heck反应，得到9,10‑二(3‑丙烯酸乙酯基)蒽(化合物2)；将化合物2与第二钯催化剂、还原剂和第二有机溶剂混合，进行加氢反应，得到9,10‑二(3‑丙酸乙酯基)蒽(化合物3)；将化合物3与3‑氨基‑1,2‑丙二醇和醇溶剂混合，进行胺酯交换反应，得到最终产物DHPA。本发明在制备DHPA时，均采用常见试剂，原料成本低；制备工艺短，收率高达85％；安全、操作方便，适合于大规模工业化生产。

  公开号：

  CN109796362A

文献信息

• POLYMERIZABLE TRIPTYCENE DERIVATIVE COMPOUND
  申请人：SEED CO., LTD.

  公开号：US20190177263A1

  公开（公告）日：2019-06-13

  It is an objective of the present invention to provide a novel polymerizable triptycene derivative that has a structure in which three benzene rings arranged at the axis formed by barrelene of the triptycene skeleton can rotate evenly and that has hydrophilicity imparted to it as compared to any of the prior art triptycene derivatives and is thus highly useful in functional materials. The above objective is achieved by the polymerizable triptycene derivative having substituents with an unsaturated bonding functional group at position 9 and/or position 10 of the triptycene skeleton, the polymerizable triptycene derivative having two carboxyl groups and the polymerizable triptycene derivative having one carboxyl group and one amino group.

  本发明的目标是提供一种新型的可聚合的三环戊二烯衍生物，其结构中三个苯环排列在三环戊二烯骨架的轴线上形成的桶烯上可以均匀旋转，并且相比于任何先前的三环戊二烯衍生物具有较高的亲水性，因此在功能材料中非常有用。通过在三环戊二烯骨架的第9位和/或第10位具有含有不饱和键的功能基团的取代基的可聚合三环戊二烯衍生物，含有两个羧基团的可聚合三环戊二烯衍生物以及含有一个羧基团和一个氨基团的可聚合三环戊二烯衍生物实现了上述目标。
• Synthesis of a hydrophilic and non-ionic anthracene derivative, the N,N′-di-(2,3-dihydroxypropyl)-9,10-anthracenedipropanamide as a chemical trap for singlet molecular oxygen detection in biological systems
  作者：Glaucia R. Martinez、Flávia Garcia、Luiz H. Catalani、Jean Cadet、Mauricio C.B. Oliveira、Graziella E. Ronsein、Sayuri Miyamoto、Marisa H.G. Medeiros、Paolo Di Mascio

  DOI：10.1016/j.tet.2006.08.094

  日期：2006.11

  We report herein the synthesis of a new hydrophilic and non-ionic anthracene derivative, the N,N′-di-(2,3-dihydroxypropyl)-9,10-anthracenedipropanamide. The evaluation of this compound as chemical trap of singlet molecular oxygen by using labeling experiments and HPLC–MS analysis showed that it could be efficiently used in biological investigations.

  我们在本文中报道了新的亲水性和非离子型蒽衍生物，N，N′-二-（2，3-二羟丙基）-9，10-蒽二丙酰胺的合成。通过标记实验和HPLC-MS分析，对该化合物作为单线态分子氧的化学阱进行了评估，结果表明该化合物可有效地用于生物学研究。
• Polymer including polymerizable triptycene derivative compound as component
  申请人：SEED CO., LTD.

  公开号：US11292762B2

  公开（公告）日：2022-04-05

  It is an objective of the present invention to provide a polymer compound as constituent component a polymerizable triptycene derivative and that has a structure in which three benzene rings arranged at the axis formed by barrelene of the triptycene skeleton can rotate evenly and that has hydrophilicity imparted to it as compared to any of the prior art triptycene derivatives and is thus highly useful in functional materials. The above objective is achieved by the polymerizable triptycene derivative and a polymer compound as constituent component thereof having substituents with an unsaturated bonding functional group at position 9 and/or position 10 of the triptycene skeleton, the polymerizable triptycene derivative having two carboxyl groups and the polymerizable triptycene derivative having one carboxyl group and one amino group.

  本发明的目标是提供一种聚合三苯基衍生物作为聚合三苯基衍生物的组成成分的聚合物化合物，其结构中三个苯环均匀旋转，排列在三苯基骨架的桶烯轴线上，并且相对于任何先前的三苯基衍生物具有亲水性，因此在功能材料中非常有用。通过在三苯基骨架的9位和/或10位上具有不饱和键功能基团的取代基，实现了上述目标，聚合三苯基衍生物具有两个羧基和聚合三苯基衍生物具有一个羧基和一个氨基。
• POLYMERIZABLE TRIPTYCENE DERIVATIVE COMPOUND, AND POLYMER COMPOUND INCLUDING SAME AS CONSTITUENT COMPONENT
  申请人：SEED CO., LTD.

  公开号：US20200369596A1

  公开（公告）日：2020-11-26

  It is an objective of the present invention to provide a novel polymerizable triptycene derivative and a polymer compound as constituent component thereof that has a structure in which three benzene rings arranged at the axis formed by barrelene of the triptycene skeleton can rotate evenly and that has hydrophilicity imparted to it as compared to any of the prior art triptycene derivatives and is thus highly useful in functional materials. The above objective is achieved by the polymerizable triptycene derivative and a polymer compound as constituent component thereof having substituents with an unsaturated bonding functional group at position 9 and/or position 10 of the triptycene skeleton, the polymerizable triptycene derivative having two carboxyl groups and the polymerizable triptycene derivative having one carboxyl group and one amino group.

  本发明的目的是提供一种新型的可聚合三苯三环衍生物和作为其组成成分的聚合物化合物，其结构中三个苯环在三苯三环骨架的桶烯形成的轴线上均匀旋转，并且具有相对于任何先前的三苯三环衍生物具有亲水性的结构，在功能材料中非常有用。通过在三苯三环骨架的位置9和/或位置10处具有含有不饱和键功能基团的取代基，实现了上述目标，聚合性三苯三环衍生物具有两个羧基，聚合性三苯三环衍生物具有一个羧基和一个氨基。
• Polymerizable triptycene derivative compound
  申请人：SEED CO., LTD.

  公开号：US10669226B2

  公开（公告）日：2020-06-02

  It is an objective of the present invention to provide a novel polymerizable triptycene derivative that has a structure in which three benzene rings arranged at the axis formed by barrelene of the triptycene skeleton can rotate evenly and that has hydrophilicity imparted to it as compared to any of the prior art triptycene derivatives and is thus highly useful in functional materials. The above objective is achieved by the polymerizable triptycene derivative having substituents with an unsaturated bonding functional group at position 9 and/or position 10 of the triptycene skeleton, the polymerizable triptycene derivative having two carboxyl groups and the polymerizable triptycene derivative having one carboxyl group and one amino group.

  本发明的目的是提供一种新型可聚合三庚烯衍生物，该衍生物具有在三庚烯骨架的筒烯形成的轴上排列的三个苯环可以均匀旋转的结构，与任何现有技术的三庚烯衍生物相比，该衍生物具有亲水性，因此在功能材料中非常有用。 可聚合的三庚烯衍生物在三庚烯骨架的第 9 位和/或第 10 位具有不饱和键合官能团的取代基，可聚合的三庚烯衍生物具有两个羧基，可聚合的三庚烯衍生物具有一个羧基和一个氨基，这些都可以达到上述目的。