2-iodophenyl 2-naphthyl sulfide | 1520814-76-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-iodophenyl 2-naphthyl sulfide
• 英文别名: (2-iodophenyl)(naphthalen-2-yl)sulfane；2-(2-Iodophenyl)sulfanylnaphthalene
• CAS: 1520814-76-9
• 化学式: C₁₆H₁₁IS
• 分子量: 362.234
• InChiKey: LPFUANREOLZHIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-iodophenyl 2-naphthyl sulfide 在 tris-(dibenzylideneacetone)dipalladium(0) 、 copper diacetate 、 特戊酸钠 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 以53%的产率得到苯并萘(1,2-D)噻唑
  参考文献：
  名称：

  Palladium Catalyzed Syntheses of Dibenzothiophenes by Ring-Closure of 2-Iodinated Diaryl Thioether

  摘要：

  An efficient ring-closure of 2-iodinated diaryl thioethers at the presence of palladium catalyst to form dibenzothiophene is described. After the best condition was set up as Pd-3(dba)(2) as the catalyst, anhydrous Cu(OAc)(2) as additive, PivONa center dot H2O as base, DMF as solvent, a series of dibenzothiophenes could be successfully obtained through this protocol in moderate to excellent yields.

  DOI：

  10.3987/com-16-13531
• 作为产物：
  描述：

  1,2-二碘苯 、 2-萘硫醇 在 N-甲基苯甲酰胺 、 sodium hydride 作用下， 以 四氢呋喃 、 N,N-二甲基乙酰胺 、 mineral oil 为溶剂， 以92 %的产率得到2-iodophenyl 2-naphthyl sulfide
  参考文献：
  名称：

  芳基硫醇或硫脲与邻二碘芳烃/NaH反应生成邻碘芳基硫醚

  摘要：

  在此，我们报道了一种通过芳基机理形成 C(芳基)-S 键来合成硫醚的方法。室温下，邻二碘芳烃和 NaH 在 THF 中可以生成活性芳炔，然后导致多种芳基硫醇和硫脲的芳基化。与过渡金属催化的交叉偶联反应不同，我们的方案中没有形成双取代的副产物。邻碘芳基硫醚产品是可以转化为药学上感兴趣的分子的中间体。

  DOI：

  10.1002/adsc.202301426

文献信息

• COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME
  申请人：NICHEM FINE TECHNOLOGY CO., LTD.

  公开号：US20180155312A1

  公开（公告）日：2018-06-07

  Provided are a novel compound and an organic electronic device using the same. The novel corn pound is represented by the following Formula (I): wherein Y is an oxygen atom, a sulfur atom, or a sulfur dioxide group; X 1 and X 2 are each independently C(R a ), multiple (R a )s are the same or different, and the two (R a )s are joined together to form a first aryl ring; X 3 and X 4 are each independently C(R b ), multiple (R b )s are the same or different, and the two (R b )s are joined to form a second aryl ring or a heteroaryl ring.

  提供了一种新型化合物和使用该化合物的有机电子器件。该新型化合物由以下公式（I）表示：其中Y是氧原子、硫原子或二氧化硫基团；X1和X2分别独立地是C（Ra），多个（Ra）相同或不同，并且两个（Ra）结合在一起形成第一个芳基环；X3和X4分别独立地是C（Rb），多个（Rb）相同或不同，并且两个（Rb）结合在一起形成第二个芳基环或杂环。
• Compound and organic electronic device using the same
  申请人：NICHEM FINE TECHNOLOGY CO., LTD.

  公开号：US10693077B2

  公开（公告）日：2020-06-23

  Provided are a novel compound and an organic electronic device using the same. The novel corn pound is represented by the following Formula (I): wherein Y is an oxygen atom, a sulfur atom, or a sulfur dioxide group; X1 and X2 are each independently C(Ra), multiple (Ra)s are the same or different, and the two (Ra)s are joined together to form a first aryl ring; X3 and X4 are each independently C(Rb), multiple (Rb)s are the same or different, and the two (Rb)s are joined to form a second aryl ring or a heteroaryl ring.

  本文提供了一种新型化合物和使用该化合物的有机电子设备。新型玉米镑由下式（I）表示： 其中，Y 是氧原子、硫原子或二氧化硫基团；X1 和 X2 各自独立为 C(Ra)，多个 (Ra)s 相同或不同，两个 (Ra)s 连接在一起形成第一个芳基环；X3 和 X4 各自独立为 C(Rb)，多个 (Rb)s 相同或不同，两个 (Rb)s 连接在一起形成第二个芳基环或杂芳环。
• Copper-Catalyzed Selective Single Arylsulfanylation of Aryl Diiodides with Aryl Thiols
  作者：Jie-Ping Wan、Yunyun Liu、Hang Wang、Xiaoji Cao、Zheng Fang

  DOI：10.1055/s-0033-1338525

  日期：——

  Selective single arylsulfanylation reactions of aryl diiodides with aryl or hetaryl thiols to give a broad array of iodine-functionalized sulfides were developed. Further elaboration of the iodine-containing products to provide a variety of aryl and hetaryl sulfides through coupling reactions was also demonstrated.