3-phenyl-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] | 1344030-90-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-phenyl-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene]
• CAS: 1344030-90-5
• 化学式: C₄₉H₃₀
• 分子量: 618.777
• InChiKey: IBWFXYTUPPBUQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.82
• 重原子数：
  49.0
• 可旋转键数：
  2.0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  9-([1,2':6',2''-ternaphthalen]-8-yl)-9H-fluoren-9-ol 在 盐酸 、 四(三苯基膦)钯 、 溴 、 potassium carbonate 、 溶剂黄146 作用下， 以 四氢呋喃 、 四氯化碳 、 水 为溶剂， 反应 12.0h， 生成 3-phenyl-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene]
  参考文献：
  名称：

  Deep blue organic light-emitting diode using non anthracene-type fused-ring spiro[benzotetraphene-fluorene] with aromatic wings

  摘要：

  We prepared three spirobenzotetraphene-based fused-ring spiro[benzo[ij]tetraphene-7,9'-fluorene] (SBTF) derivatives for use in non anthracene-type deep-blue organic light-emitting diode (OLED) hosts. 3-(2-Naphthyl)-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] (N-NSBTF), 3-[4-(2-naphthyl)phenyl]-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] (NP-NSBTF), and 3-(phenyl)-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] (P-NSBTF) were synthesized via multi-step Suzuki coupling reactions. The optimized device structure - ITO/N,N'-bis-[4-(di-m-tolylamino)phenyl]-N,N'-diphenylbiphenyl-4,4'-diamine (DNTPD, 60 nm)/bis[N-(1-naphthyl)-N-phenyl]benzidine (NPB, 30 nm)/NSBTF hosts: LBD (5%) (20 nm)/aluminum tris(8-hydroxyquinoline) (Alq(3), 20 nm)/LiF/Al - was characterized by its blue electroluminescence to have a current efficiency of 6.25 cd/A, a power efficiency of 5.07 lm/W, and an external quantum efficiency of 5.24% at 18.7 mA/cm(2) at CIE coordinates of 0.130, 0.149. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2014.08.030

文献信息

• [EN] NOVEL AROMATIC DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING SAME<br/>[FR] NOUVEAUX DÉRIVÉS AROMATIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES COMPRENANT
  申请人：DAEJOO ELECTRONIC MAT CO LTD

  公开号：WO2010038956A3

  公开（公告）日：2010-07-22