9-Acetyl-cis-decalin | 5682-42-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 9-Acetyl-cis-decalin
• CAS: 5682-42-8
• 化学式: C₁₂H₂₀O
• 分子量: 180.29
• InChiKey: SUJSKPGASDUIMZ-TXEJJXNPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.33
• 重原子数：
  13.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  9-Acetyl-cis-decalin 在 lithium aluminium tetrahydride 作用下， 生成 Methyl--carbinol
  参考文献：
  名称：

  9-Decalyl free radicals. Decomposition of cis- and trans-9-decalylcarbinyl hypochlorite

  摘要：

  DOI：

  10.1021/jo01279a005
• 作为产物：
  描述：

  cis-decalin-9-carboxylic acid 以 乙醚 为溶剂， 生成 9-Acetyl-cis-decalin
  参考文献：
  名称：

  9-Decalyl free radicals. Decomposition of cis- and trans-9-decalylcarbinyl hypochlorite

  摘要：

  DOI：

  10.1021/jo01279a005

文献信息

• Hydroxymethyl-group-containing alicyclic compound and process for producing the same
  申请人：Daicel Chemical Industries, Ltd.

  公开号：US06576787B1

  公开（公告）日：2003-06-10

  Hydroxymethyl-group-containing alicyclic compounds that are useful for making photosensitive resins and other functional polymers. Processes for producing the hydroxymethyl-group-containing alicyclic compounds. Polymerizable alicyclic compounds. The alicyclic moieties in all of these compounds may be a polycyclic ring such as a perhydroindene ring, a decalin ring, a perhydrofluorene ring, a perhydroanthracene ring, a perhydrophenanthrene ring, a tricyclo[5.2.1.02.6]decane ring, a perhydroacenaphthene ring, or a perhydrophenalene ring.

  含有羟甲基基团的脂环化合物可用于制备光敏树脂和其他功能性聚合物。制备含有羟甲基基团的脂环化合物的方法。可聚合的脂环化合物。所有这些化合物中的脂环基团可以是多环环烷环，例如过氢化吲哚环，十二烷环，过氢化芴环，过氢化蒽环，过氢化菲环，三环[5.2.1.02.6]癸烷环，过氢化苊并环或过氢化苯并芘环。
• Methods of acylating adamantane, tricyclo[5.2.1.02,6], and decalin compounds
  申请人：Daicel Chemical Industries, Ltd.

  公开号：US06429314B1

  公开（公告）日：2002-08-06

  An acylating agent of the invention includes (A) a 1,2-dicarbonyl compound or its hydroxy reductant, (B) oxygen, and (C) at least one compound selected from (c1) a metallic compound and (C2) N-hydroxyphthalimide or another imide compound. As the 1,2-dicarbonyl compound or its hydroxy reductant (A), biacetyl, 2,3-butanediolor the like canbeused. As the metallic compound (c1), cobalt acetate, or another cobalt compound, for example, can be employed. By reacting an adamantane derivative or another compound having a methine carbon atom with the acylating agent, an acyl group can be introduced to the methine carbon atom with efficiency.

  本发明的酰化剂包括（A）1,2-二羰基化合物或其羟基还原剂，（B）氧气，以及（C）至少选择自（c1）金属化合物和（C2）N-羟基邻苯二酰亚胺或其他亚酰胺化合物。作为1,2-二羰基化合物或其羟基还原剂（A），可以使用丙二酮，2,3-丁二醇或类似物。作为金属化合物（c1），可以使用醋酸钴或其他钴化合物。通过将金刚烷衍生物或具有甲烷碳原子的其他化合物与酰化剂反应，可以高效地引入酰基到甲烷碳原子。
• ACYLATING AGENTS, ACYLATION METHOD WITH THE USE OF THE SAME AND ADAMANTANE DERIVATIVES
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP0990634A1

  公开（公告）日：2000-04-05

  An acylating agent of the invention includes (A) a 1,2-dicarbonyl compound or its hydroxy reductant, (B) oxygen, and (C) at least one compound selected from (c1) a metallic compound and (C2) N-hydroxyphthalimide or another imide compound. As the 1,2-dicarbonyl compound or its hydroxy reductant (A), biacetyl, 2,3-butanediol or the like can be used. As the metallic compound (c1), cobalt acetate, or another cobalt compound, for example, can be employed. By reacting an adamantane derivative or another compound having a methine carbon atom with the acylating agent, an acyl group can be introduced to the methine carbon atom with efficiency.

  本发明的酰化剂包括(A)1,2-二羰基化合物或其羟基还原剂，(B)氧和(C)至少一种选自(c1)金属化合物和(C2)N-羟基邻苯二甲酰亚胺或另一种酰亚胺化合物的化合物。作为 1,2-二羰基化合物或其羟基还原剂 (A)，可以使用生物乙酰基、2,3-丁二醇或类似物。作为金属化合物（c1），可以使用醋酸钴或其他钴化合物等。将金刚烷衍生物或其他具有甲烷碳原子的化合物与酰化剂反应，可以有效地将酰基引入甲烷碳原子。
• ALICYCLIC COMPOUNDS CONTAINING HYDROXYMETHYL GROUP, PROCESS FOR PRODUCING THE SAME, AND POLYMERIZABLE ALICYCLIC COMPOUND
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1070699A1

  公开（公告）日：2001-01-24

  Hydroxymethyl-containing alicyclic compounds represented by formula (1) or (2), wherein rings A, B, C, D, and E each represents a nonaromatic carbon ring; Ra and Rb each represents hydrogen or a hydrocarbon group and at least one of Ra and Rb is a hydrocarbon group; and Rc, Rd, and Re each represents hydrogen, halogeno, alkyl, hydroxyl optionally protected by a protective group, hydroxymethyl optionally protected by a protective group, amino optionally protected by a protective group, carboxyl optionally protected by a protective group, nitro, acyl, or a group represented by formula (3) (wherein Ra and Rb have the same meanings as the above).

  由式(1)或(2)代表的含羟甲基脂环族化合物，其中环 A、B、C、D 和 E 各代表一个非芳香族碳环；Ra 和 Rb 各代表氢或烃基，且 Ra 和 Rb 中至少有一个是烃基；Rc、Rd 和 Re 各自代表氢、卤素、烷基、任选受保护基团保护的羟基、任选受保护基团保护的羟甲基、任选受保护基团保护的氨基、任选受保护基团保护的羧基、硝基、酰基或式 (3) 所代表的基团（其中 Ra 和 Rb 的含义与上述相同）。
• PROCESS FOR THE PREPARATION OF ORGANIC COMPOUNDS WITH IMIDE CATALYSTS
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1055654B1

  公开（公告）日：2008-02-20