[Cu(3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline)2(NO3)2] | 927189-35-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Cu(3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline)2(NO3)2]
• CAS: 927189-35-3
• 化学式: C₃₆H₃₄CuN₈O₆
• 分子量: 738.262
• InChiKey: MIRPNCJSIOAWQU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline 、 copper(II) nitrate trihydrate 以 乙腈 为溶剂， 生成 [Cu(3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline)2(NO3)2]
  参考文献：
  名称：

  Complexes of Cu(II) and Co(II) nitrates with 3-Phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline

  摘要：

  Complexes of Cu(Il) and Co(II) nitrates with 3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-alisoquinoline (L-0) of the composition [CuL20 (NO3)(2)] (I) and [CoL20(NO3)(2)] center dot CH3CN are synthesized and their crystal structures are determined by X-ray diffraction. The L-0 ligand is coordinated to the metal atoms through the N atom in position 2 of triazole fragment. The coordination polyhedron of the Cu(II) atom is a square with two additional axial vertices, while that of the Co(II) atom is a tetrahedron with two additional vertices. The NO3- groups in the structures of I and II perform similar anisobidentate function. Complexes I and II are studied by IR and electronic spectroscopy.

  DOI：

  10.1134/s1070328406060030