4-(2'F-Hexyethyl)amino benzoate | 157103-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2'F-Hexyethyl)amino benzoate
• CAS: 157103-01-0
• 化学式: C₁₅H₁₀F₁₃NO₂
• 分子量: 483.229
• InChiKey: FPCAWANGAPWGAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.55
• 重原子数：
  31.0
• 可旋转键数：
  8.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  52.32
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  4-(2'F-Hexyethyl)amino benzoate 在 sodium acetate 、 乙酸酐 作用下， 以 氯仿 为溶剂， 反应 2.0h， 生成 Maleimide
  参考文献：
  名称：

  Grafting of fluorinated oligomers on to high-density polyethylene (HDPE) in the molten state

  摘要：

  The grafting reaction of fluorinated maleamic acid and maleimide oligomers on to high-density polyethylene (HDPE) in the molten state is described. Temperature and roller speed play an important role since the greater these are, the greater the grafting rate. The same compounds have also been grafted using an initiator under the same conditions. It has been shown that the maleimide forms are more reactive than maleamic acid. This can be explained by steric hindrance which decreases the grafting rate. The use of an initiator favours grafting.

  DOI：

  10.1016/0022-1139(94)03214-k
• 作为产物：
  描述：

  3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇 在 palladium on activated charcoal 吡啶 、 一水合肼 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 为溶剂， 反应 23.5h， 生成 4-(2'F-Hexyethyl)amino benzoate
  参考文献：
  名称：

  Synthesis of graft copolymers of polyethylene: grafting of fluorinated model compound oligomers

  摘要：

  The condensation reaction of perfluorinated amines on to (succinic anhydride)-HDPE (high-density polyethylene) graft copolymer have been studied. Four different amine structures have been synthesized which have been analyzed by H-1 NMR spectroscopy GC-MS methods. Model structures of succinimide and succinamic acid have been synthesized with each amine and analyzed by FT-IR spectroscopy in order to determine the structure of the copolymer obtained. A scale of reactivity has been deduced as a function of the amine structure. Grafting levels of copolymer have been determined by elemental analysis of fluorine.

  DOI：

  10.1016/0022-1139(93)03043-l