cobalt tetra-5-nitrotetra-4-(4-carboxyphenoxy)phthalocyanine | 478021-25-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cobalt tetra-5-nitrotetra-4-(4-carboxyphenoxy)phthalocyanine
• 英文别名: cobalt [tetra-4-nitro-tetra-5-(4-carboxyphenoxy)]phthalocyanine
• CAS: 478021-25-9
• 化学式: C₆₀H₂₈CoN₁₂O₂₀
• 分子量: 1295.94
• InChiKey: HNERNKCSCBEUKR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) acetate 、 4-(4,5-dicyano-2-nitrophenoxy)benzoic acid 以 neat (no solvent) 为溶剂， 以54%的产率得到cobalt tetra-5-nitrotetra-4-(4-carboxyphenoxy)phthalocyanine
  参考文献：
  名称：

  摘要：

  A series of aryloxy-substituted phthalodinitriles were prepared by nucleophilic aromatic substitution of bromine in 4-bromo-5-nitrophthalodinitrile, and the corresponding phthalocyanines were synthesized, The physicochemical properties of phthalocyanines depend on the substituent in the aryl moiety.

  DOI：

  10.1023/a:1015454508883

文献信息

• Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity
  作者：Artur Vashurin、Vladimir Maizlish、Ilya Kuzmin、Serafima Znoyko、Anastasiya Morozova、Mikhail Razumov、Oscar Koifman

  DOI：10.1142/s108842461750002x

  日期：2017.1

  Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium [Formula: see text],[Formula: see text]-carbomoditiolate were investigated.

  通过亲核取代 4-溴-5-硝基邻苯二甲腈中的溴基和硝基，以 4-氨基、4-羟基和 4-硫基苯甲酸为残基，合成了不同官能团和对称的邻苯二甲腈。以上述酞腈为基础，通过模板合成法获得了对称和双官能团取代的酞菁钴。研究了这些酞菁在有氧氧化[式：见正文]、[式：见正文]-碳二硫醇钠时的光谱特性和催化活性。
• Bifunctionally Substituted Cobalt(II) Phthalocyanines with Benzoic Acid Fragments
  作者：A. P. Morozova、S. A. Znoiko、A. S. Vashurin、A. V. Zav’yalov、V. E. Maizlish、G. P. Shaposhnikov

  DOI：10.1134/s1070363217120544

  日期：2017.12

  Phthalonitriles with fragments of 4-amino-, 4-hydroxy-, and 4-sulfanylphenylbenzoic acids were synthesized by nucleophilic substitution in 4-bromo-5-nitrophthalonitrile. A disubstituted phthalonitrile containing 1H-1,2,3-benzotriazole and p-hydroxybenzoic acid fragments was obtained by the substitution of the nitro group in 4-(4-carboxyphenoxy)-5-nitrophthalonitrile by a 1H-1,2,3-benzotriazol-1-yl group. The synthesized phthalocyanines were used as starting materials in the template synthesis of bifunctional cobalt phthalocyanines. Spectral properties of the latter products were studied.