| 249927-60-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 249927-60-4
• 化学式: C₇₁H₇₁O₂₀P
• 分子量: 1275.31
• InChiKey: DHXDVFGGVCZVAE-HCCVUOMNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.23
• 重原子数：
  92.0
• 可旋转键数：
  30.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  247.32
• 氢给体数：
  0.0
• 氢受体数：
  20.0

反应信息

• 作为反应物：
  描述：

  2,2,2-三氟-N,N-二(三甲硅基)乙酰胺 、 以 四氢呋喃 为溶剂， 生成 (2R,3S,4S,5R,6S)-2-((benzoyloxy)methyl)-6-(((2R,3R,4S,5S,6R)-4,5-bis(benzoyloxy)-2-((benzoyloxy)methyl)-6-(((decyloxy)((trimethylsilyl)oxy)phosphaneyl)oxy)tetrahydro-2H-pyran-3-yl)oxy)tetrahydro-2H-pyran-3,4,5-triyl tribenzoate
  参考文献：
  名称：

  Synthesis of novel glycosyl phosphate analogues: Derivatives of an acceptor substrate for the Leishmania elongating α-d-mannopyranosylphosphate transferase

  摘要：

  The three structural analogues of dec-9-enyl beta-D-galactosyl-(1-->4)-alpha-D-mannosyl phosphate, comprising thiophosphate, boranophosphate and methylphosphonate derivatives, were prepared via disaccharide H-phosphonate or trichloroacetimidate (for the methylphosphonate synthesis) intermediates. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01381-7
• 作为产物：
  描述：

  癸醇 、 在 吡啶 、 三甲基乙酰氯 作用下， 生成
  参考文献：
  名称：

  Synthesis of novel glycosyl phosphate analogues: Derivatives of an acceptor substrate for the Leishmania elongating α-d-mannopyranosylphosphate transferase

  摘要：

  The three structural analogues of dec-9-enyl beta-D-galactosyl-(1-->4)-alpha-D-mannosyl phosphate, comprising thiophosphate, boranophosphate and methylphosphonate derivatives, were prepared via disaccharide H-phosphonate or trichloroacetimidate (for the methylphosphonate synthesis) intermediates. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01381-7