[Zn(Se2P(OPr)2)2]2 | 797058-28-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Zn(Se2P(OPr)2)2]2
• CAS: 797058-28-7
• 化学式: C₂₄H₅₆O₈P₄Se₈Zn₂
• 分子量: 1359.06
• InChiKey: BXVRJNVAIGDEKV-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  [Zn4(μ4-Se)(Se2P(O(n)Pr)2)6] 以 二氯甲烷-D2 为溶剂， 生成 [Zn(Se2P(OPr)2)2] 、 [Zn(Se2P(OPr)2)2]2
  参考文献：
  名称：

  The First, Discrete Zn₄ Tetrahedron with a Selenium Atom in the Center:  X-ray Structure and Solution Study of [Zn₄(μ₄-Se){Se₂P(OPr)₂}₆]

  摘要：

  The first discrete, selenium-centered tetranuclear zinc cluster [Zn-4(mu(4)-Se){Se2P(OPr)(2)}(6)] was isolated and characterized. The cluster consists of six edge-bridged clsep ligands with four zinc atoms in a slightly distorted tetrahedron and a mu(4)-Se atom in the center. In addition, 12 mu(2)-bridging selenium atoms form a Se-12 icosahedron. From variable-temperature P-31 NMR studies, it was observed that the cluster [Zn-4(Se){Se2P(OPr)(2)}(6)] is partly decomposed to [ZnSe2P(OPr)(2)}(2)] and the monomeric species [Zn4Se2P(OPr)(2)}(2)] is further in equilibrium with its dimer [Zn{Se2P(OPr)(2)}(2)](2).

  DOI：

  10.1021/ic048791j