9-(3-trichlorosilylprop-1-yl)carbazole | 866454-41-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(3-trichlorosilylprop-1-yl)carbazole
• 英文别名: 3-carbazol-9-ylpropyl(trichloro)silane
• CAS: 866454-41-3
• 化学式: C₁₅H₁₄Cl₃NSi
• 分子量: 342.727
• InChiKey: BONDNCHCVVYGAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.84
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,6-bis(9-methylcarbazol-3-yl)-9-allylcarbazole 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 、 三氯硅烷 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 2.0h， 以5.6 g的产率得到9-(3-trichlorosilylprop-1-yl)carbazole
  参考文献：
  名称：

  AN ELECTROCHROMIC COMPOSITION, A METHOD OF FORMING THE ELECTROCHROMIC COMPOSITION AND AN ELECTROCHROMIC APPARATUS

  摘要：

  公开号：

  EP2231814B1

文献信息

• Organic light-emitting diode
  申请人：Schalk Paul

  公开号：US20070090359A1

  公开（公告）日：2007-04-26

  An organic light-emitting diode comprising a substrate having a first opposing surface and a second opposing surface; a first electrode layer overlying the first opposing surface; a light-emitting element overlying the first electrode layer, the light-emitting element comprising a hole-transport layer and an emissive/electron-transport layer, wherein the hole-transport layer and the emissive/electron-transport layer lie directly on one another, and the hole-transport layer comprises a cured polysiloxane prepared by applying an organosilicon composition to form a film and exposing the film to moisture to form the cured polysiloxane, wherein the organosilicon composition comprises at least one silane having a group selected from carbazolyl, fluoroalkyl, and pentafluorophenylalkyl; and a second electrode layer overlying the light-emitting element.

  一种有机发光二极管，包括具有第一对立面和第二对立面的基板；第一电极层覆盖在第一对立面上；发光元件覆盖在第一电极层上，发光元件包括一个空穴传输层和一个发射/电子传输层，其中空穴传输层和发射/电子传输层直接相互叠放，并且空穴传输层包括通过将有机硅组分涂覆成膜，并暴露于水分以形成固化聚硅氧烷的方法制备的固化聚硅氧烷，其中有机硅组分包括至少一种具有从卡巴唑基，氟代烷基和五氟苯基烷基中选择的基团的硅烷；第二电极层覆盖在发光元件上。
• Electrochromic Composition, A Method Of Forming The Electrochromic Composition And An Electrochromic Apparatus
  申请人：Witker David

  公开号：US20100284053A1

  公开（公告）日：2010-11-11

  An electrochromic apparatus comprises a first electrode layer and a second electrode layer spaced from and disposed substantially parallel to the first electrode. An electrochromic layer is disposed between the first and second electrode layers. An electrolyte layer is disposed between the electrochromic layer and one of the electrode layers. The electrochromic layer comprises the dehydration reaction product of a hydrolyzed aromatic component. An electrochromic composition comprises an aromatic component having an aromatic core and at least two silicon-based groups pending from the aromatic core. The silicon-based groups have a silicon-bonded group selected from the group of hydrolyzable groups, hydrolyzates of hydrolyzable groups, and combinations thereof. The thickness of the electrochromic layer may be minimized while achieving desirable electrochromic properties that are typically characteristic of thicker electrochromic layers, thereby imparting the electrochromic apparatus with excellent versatility and flexibility.

  一种电致变色装置包括第一电极层和第二电极层，与第一电极间隔并且基本平行地放置的第二电极层。电致变色层位于第一和第二电极层之间。电解质层位于电致变色层和其中一个电极层之间。电致变色层包含水解芳香组分的脱水反应产物。一种电致变色组合物包括具有芳香核和至少两个从芳香核悬挂的基于硅的基团的芳香组分。这些硅基基团具有从可水解基团、可水解基团的水解产物和它们的组合中选择的硅键合基团。通过最小化电致变色层的厚度，同时实现通常特征较厚电致变色层的理想电致变色性能，从而赋予电致变色装置出色的多功能性和灵活性。
• Electrochromic composition, a method of forming the electrochromic composition and an electrochromic apparatus
  申请人：Witker David

  公开号：US08564871B2

  公开（公告）日：2013-10-22

  An electrochromic apparatus comprises a first electrode layer and a second electrode layer spaced from and disposed substantially parallel to the first electrode. An electrochromic layer is disposed between the first and second electrode layers. An electrolyte layer is disposed between the electrochromic layer and one of the electrode layers. The electrochromic layer comprises the dehydration reaction product of a hydrolyzed aromatic component. An electrochromic composition comprises an aromatic component having an aromatic core and at least two silicon-based groups pending from the aromatic core. The silicon-based groups have a silicon-bonded group selected from the group of hydrolyzable groups, hydrolyzates of hydrolyzable groups, and combinations thereof. The thickness of the electrochromic layer may be minimized while achieving desirable electrochromic properties that are typically characteristic of thicker electrochromic layers, thereby imparting the electrochromic apparatus with excellent versatility and flexibility.

  一种电致变色装置包括第一电极层和第二电极层，与第一电极相距且基本平行地放置的第二电极。电致变色层位于第一和第二电极层之间。电解质层位于电致变色层和其中一个电极层之间。电致变色层包括水解芳香组分的脱水反应产物。一种电致变色组合物包括具有芳香核和至少两个从芳香核中悬挂的基于硅的基团的芳香组分。硅基基团具有从可水解基团、可水解基团的水解产物和它们的组合中选择的硅键合基团。电致变色层的厚度可以最小化，同时实现通常特征为较厚电致变色层的理想电致变色性能，从而赋予电致变色装置出色的多功能性和灵活性。