2-methyl-9-(2-naphthyl)-10-bromoanthracene | 1087379-95-0

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2-methyl-9-(2-naphthyl)-10-bromoanthracene
• 英文别名: 10-Bromo-2-methyl-9-naphthalen-2-ylanthracene
• CAS: 1087379-95-0
• 化学式: C₂₅H₁₇Br
• 分子量: 397.314
• InChiKey: ULENXCUGOAZCIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-methyl-9-(2-naphthyl)-10-bromoanthracene 、 4-联苯硼酸 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以90.3%的产率得到2-methyl-9-(2-naphthyl)-10-(4-biphenyl)anthracene
  参考文献：
  名称：

  Unsymmetrically amorphous 9,10-disubstituted anthracene derivatives for high-efficiency blue organic electroluminescence devices

  摘要：

  Two unsymmetrically amorphous 9,10-disubstituted anthracene derivatives have been synthesized and characterized. They emit the light in the blue region and possess glass transition temperature of 132.5 degrees C and 133.8 degrees C. The scanning electron microscope (SEM) was employed in studying the thin-film morphological stability of the two unsymmetrical isomers. These two compounds were fabricated into typical trilayers devices with pure blue lighting performance. In addition, a series of highly efficient and stable sky blue devices doped with a sky blue dopant BUBD-1 have been fabricated by using these two isomers as the host. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.10.007
• 作为产物：
  描述：

  2-methyl-9-(2-naphthyl)anthracene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以85.4%的产率得到2-methyl-9-(2-naphthyl)-10-bromoanthracene
  参考文献：
  名称：

  Unsymmetrically amorphous 9,10-disubstituted anthracene derivatives for high-efficiency blue organic electroluminescence devices

  摘要：

  Two unsymmetrically amorphous 9,10-disubstituted anthracene derivatives have been synthesized and characterized. They emit the light in the blue region and possess glass transition temperature of 132.5 degrees C and 133.8 degrees C. The scanning electron microscope (SEM) was employed in studying the thin-film morphological stability of the two unsymmetrical isomers. These two compounds were fabricated into typical trilayers devices with pure blue lighting performance. In addition, a series of highly efficient and stable sky blue devices doped with a sky blue dopant BUBD-1 have been fabricated by using these two isomers as the host. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.10.007

文献信息

• BENZANTHRACENE DERIVATIVES FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Stoessel Philipp

  公开号：US20100187505A1

  公开（公告）日：2010-07-29

  The present invention relates to the compounds of the formula (1) and to organic electroluminescent devices, in particular blue-emitting devices, in which these compounds are used as host material or dopant in the emitting layer and/or as hole-transport material and/or as electron-transport material.

  本发明涉及公式（1）的化合物，以及有机电致发光器件，特别是蓝色发光器件，在这些器件中，这些化合物被用作发射层的主体材料或掺杂剂，和/或作为空穴传输材料和/或电子传输材料。
• US8986852B2
  申请人：——

  公开号：US8986852B2

  公开（公告）日：2015-03-24