Zn(1-hydroxymethyl-4-imidazoleacetate)2(H2O)2 | 848033-22-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Zn(1-hydroxymethyl-4-imidazoleacetate)2(H2O)2
• CAS: 848033-22-7
• 化学式: C₁₂H₁₈N₄O₈Zn
• 分子量: 411.687
• InChiKey: DFAIAYNRUCQERF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 水 、 zinc(II) acetate dihydrate 、 5-imidazoleacetate 生成 Zn(1-hydroxymethyl-4-imidazoleacetate)2(H2O)2
  参考文献：
  名称：

  Synthesis and crystal structures of metal complexes with 4,5-imidazole-dicarboxylate chelates: self-assembled structures via NH⋯O C intermolecular hydrogen bonds

  摘要：

  New metal complexes with two imidazole-carboxylate sets, [Zn(hmia)(2)(H2O)(2)] (hmia = 1-hydroxymethyl-4-imidazoleacetate) (1) and [M(Himdc)(2)(H2O)(2)] (imdc = 4,5-imidazoledicarboxylate) (M = Zn (2), Co (3), Cu (4)), were synthesized and structurally characterized. For all metal complexes, coordination of the two N-O sets of chelating ligands and two water molecules produces a distorted (1-3) and an elongated (4) octahedral coordination center, in which these monomeric units are connected by various intermolecular hydrogen bonds. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.09.008