(Z)-2-iodohex-2-ene | 343949-82-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: (Z)-2-iodohex-2-ene
• CAS: 343949-82-6
• 化学式: C₆H₁₁I
• 分子量: 210.058
• InChiKey: FZNALXCEINWZOD-WAYWQWQTSA-N

物化性质

• 沸点：
  164.6±9.0 °C(Predicted)
• 密度：
  1.502±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (Z)-2-iodohex-2-ene 在 锰 、 二氯二茂锆 、 [(2,9-dimethyl-1,10-phenanthroline)dichloro nickel(II)] 、 lithium chloride 作用下， 以 乙二醇二甲醚 为溶剂， 生成 、
  参考文献：
  名称：

  Catalytic homocoupling of aryl, alkenyl, and alkynyl halides with Ni(II)-complexes and zirconocene dichloride

  摘要：

  A new catalytic system (cat. (H)(2)Phen(Me)(2)center dot NiCl(2) or (MeO)(2)Dipyr(H)(2)center dot NiCl(2), cat. Zr(cp)(2)Cl(2), 2 equiv Mn, and 2 equiv LiCl) has been developed to facilitate the homocoupling of a wide range of aryl, alkenyl, and alkynyl halides. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.11.124
• 作为产物：
  描述：

  2-已炔 生成 (Z)-2-iodohex-2-ene
  参考文献：
  名称：

  ASHBY E. C.; NODING S. A., J. ORG. CHEM., 1980, 45, NO 6, 1035-1041

  摘要：

  DOI：

文献信息

• Air-Stable Heterobimetallic Catalysts to Effect Ni/Cr-Mediated Couplings with a ca. 1:1 Molar Ratio of Coupling Partners at Low Catalyst Loadings
  作者：Jianbiao Peng、Yoshito Kishi

  DOI：10.1021/ol202878v

  日期：2012.1.6

  Two air-stable NI,Cr-heterobimetallic catalysts have been prepared from ligands 7 and 11, obtained from scyllo-inositol in four and three steps, respectively. Both catalysts smoothly promote Ni/Cr-mediated coupling reactions with a ca. 1:1 molar ratio of coupling partners. The catalyst derived from 11 exhibits a better catalytic profile, thereby allowing Ni/Cr-mediated coupling reactions to be achieved with a wide range of substrates at a low catalyst loading in an operationally simple manner.
• On Ni Catalysts for Catalytic, Asymmetric Ni/Cr-Mediated Coupling Reactions
  作者：Xiang Liu、Xiaoyong Li、Yu Chen、Yimin Hu、Yoshito Kishi

  DOI：10.1021/ja302177z

  日期：2012.4.11

  The importance of the Ni catalyst in achieving catalytic asymmetric Ni/Cr-mediated coupling reactions effectively is demonstrated. Six phenanthroline-NiCl2 complexes 1a-c and 2a-c and five types of alkenyl iodides A-E were chosen for the study, thereby demonstrating that these Ni catalysts display a wide range of overall reactivity profiles in terms of the degree of asymmetric induction, geometrical isomerization, and coupling rate. For three types of alkenyl iodides A-C, a satisfactory Ni catalyst(s) was found within 1a-c and 2a-c. For disubstituted (Z)-alkenyl iodide D, 2c was identified as an acceptable Ni catalyst: in terms of the absence of Z --> E isomerization and the degree of asymmetric induction but not in terms of the coupling rate. Two phosphine-based Ni catalysts, [(Me)(3)P](2)center dot NiCl2 and [(cy)(3)P](2)center dot NiCl2, were found to meet all three criteria for D. The bond-forming reaction at the C16-C17 position of palytoxin was used to demonstrate the usefulness of the Ni catalysts thus identified.
• ASHBY E. C.; NODING S. R., J. ORGANOMETAL. CHEM., 1979, 177, NO 1, 117-128
  作者：ASHBY E. C.、 NODING S. R.

  DOI：——

  日期：——
• SATO FUMIE; ISHIKAWA HIROAKI; SATO MASAO, TETRAHEDRON LETT., 1981, 22, NO 1, 85-88
  作者：SATO FUMIE、 ISHIKAWA HIROAKI、 SATO MASAO

  DOI：——

  日期：——