Co(2-phenyl-1H-imidazole-4,5-dicarboxylate)2(H2O) | 1403940-72-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Co(2-phenyl-1H-imidazole-4,5-dicarboxylate)2(H2O)
• CAS: 1403940-72-6
• 化学式: C₂₂H₁₆CoN₄O₉
• 分子量: 539.384
• InChiKey: FBGQSRPPTNVVLO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(II) nitrate hexahydrate 、 2-苯基-1H-咪唑-4,5-二甲酸 、 水 在 三乙胺 作用下， 反应 96.0h， 以53%的产率得到Co(2-phenyl-1H-imidazole-4,5-dicarboxylate)2(H2O)
  参考文献：
  名称：

  Syntheses, Crystal Structures, and Properties of Three Co(II) Supramolecules Constructed From Phenyl Imidazole Dicarboxylates

  摘要：

  Three mononuclear cobalt(II) complexes, [Co(H2MOPhIDC)(2)(H2O)(2)]center dot 2H(2)O (H3MOPhIDC = 2-(3-methoxyphenyl)-1H-imidazole-4,5-dicarboxylic acid) (1), [Co(H2MOPhIDC)(2)(H2O)(2)]center dot 2CH(3)CN (2), and [Co(H2PhIDC)(2)(H2O)] (3) (H3PhIDC = 2-phenyl-1H-imidazole-4,5-dicarboxylic acid), have been hydro(solvo)thermally synthesized by fine control over synthetic conditions such as solvent, pH value, and temperature. Their molecular structures have been characterized by IR spectra, elemental analyses, and thermogravimetric analyses and further characterized by single-crystal X-ray diffraction. Furthermore, the photoluminescent properties of the three complexes have been investigated.

  DOI：

  10.1080/15533174.2012.684269