2-hydroxymethyl-2-undec-10-enyloxymethyl-propane-1,3-diol | 1175537-74-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-hydroxymethyl-2-undec-10-enyloxymethyl-propane-1,3-diol
• CAS: 1175537-74-2
• 化学式: C₁₆H₃₂O₄
• 分子量: 288.428
• InChiKey: ADNLRRVFCWRYIF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  hexakis(methanolate)hexakis(dipyvaloylmethanate)tetrairon(III) 、 2-hydroxymethyl-2-undec-10-enyloxymethyl-propane-1,3-diol 以 乙醚 为溶剂， 以90%的产率得到[Fe4(2-hydroxymethyl-2-undec-10-enyloxymethyl-propane-1,3-diol(3-))6(2,2,6,6-tetramethylheptane-3,5-dionate)6]
  参考文献：
  名称：

  One pot grafting of tetrairon(III) single molecule magnets on silicon

  摘要：

  Herein we report on the Si grafting of two Fe-4 derivatives, [Fe-4(L-i)(2)(tmhd)(6)], in which tmhd is 2,2,6,6-tetramethylheptane-3,5-dionate and H3Li = R-C(CH2OH)(3) is a tripodal ligand with R = CH2 = CH-CH2-O-CH2 (H3Li) and CH2 = CH-(CH2)(9)-O-CH2 (H3L2). These complexes were specifically designed to be directly anchored on the H-terminated silicon surface via the hydrosilylation reaction. The complexes were grafted by a one pot route based on the photoinduced hydrosilylation followed by a ligand exchange step in the same reaction solution. The resulting decorated surfaces were characterized using X-ray photoelectron spectroscopy (XPS), attenuated total reflection infrared spectroscopy (ATR-IR) and atomic force microscopy (AFM). (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.049