bis[zinc(II)(μ-tri-tert-butoxysilanethiolate)acetylacetonate] | 355841-08-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis[zinc(II)(μ-tri-tert-butoxysilanethiolate)acetylacetonate]
• 英文别名: [(Zn(μ-tri-tert-butoxysilanethiolato)(acetylacetonato)]2
• CAS: 355841-08-6
• 化学式: C₃₄H₆₈O₁₀S₂Si₂Zn₂
• 分子量: 887.991
• InChiKey: VQGXMCMVUKMOBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tri-tert-butoxysilanethiol 、 zinc(II) acetylacetonate 以 乙腈 为溶剂， 以33%的产率得到bis[zinc(II)(μ-tri-tert-butoxysilanethiolate)acetylacetonate]
  参考文献：
  名称：

  Zinc tri-tert-butoxysilanethiolates. Syntheses, properties and crystal and molecular structures of [Zn{μ-SSi(OBut)3}(acac)]2 and [{(ButO)3SiS}(H2O)2Zn{μ-SSi(OBut)3}Zn(acac){SSi(OBut)3}]

  摘要：

  Heteroleptic, neutral tri-tert-butoxysilanethiolates of zinc, incorporating acetylacetonate (1) or acetylacetonate and a ater (2) as additional ligands, have been prepared by a reaction of zinc acetylacetonate with tri-tert-butoxysilanethiol in acetonitrile and characterized by IR, NMR and MS techniques. Crystal and molecular structures have been determined by single crystal X-ray structural analysis. Both are bimetallic with a distorted tetrahedral ligand arrangement at the zinc and ZnO2S2 core. Complexes 1 and 2 are the first structurally characterized thiolates where the metal is also bonded to acetylacetonate and 2 is the first neutral aqua-ligated zinc thiolate. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00748-3