(4-Chlorophenoxy)-trimethylstannane | 64128-19-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Chlorophenoxy)-trimethylstannane
• CAS: 64128-19-4
• 化学式: C₉H₁₃ClOSn
• 分子量: 291.365
• InChiKey: UBYOZCMTMFBHFN-UHFFFAOYSA-M

物化性质

• 沸点：
  137 °C(Press: 3 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  3.55
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  溴甲苯 、 (4-Chlorophenoxy)-trimethylstannane 生成 4-苄氧基氯苯
  参考文献：
  名称：

  KOZUKA SEIZI; KIKUCHI AKIHIKO; YAMAGUCHI SHIGERU, BULL. CHEM. SOC. JAP., 1981, 54, NO 1, 307-308

  摘要：

  DOI：
• 作为产物：
  描述：

  trimethyltin methoxide 、 对氯苯酚 以65%的产率得到
  参考文献：
  名称：

  KOZUKA SEIZI; KIKUCHI AKIHIKO; YAMAGUCHI SHIGERU, BULL. CHEM. SOC. JAP., 1981, 54, NO 1, 307-308

  摘要：

  DOI：

文献信息

• The Mechanism of the Reaction of (Aryloxy)trimethylstannane with Benzyl Bromide giving Aryl Benzyl Ether
  作者：Seizi Kozuka、Akihiko Kikuchi、Shigeru Yamaguchi

  DOI：10.1246/bcsj.54.307

  日期：1981.1

  A kinetic study has been performed for the reaction of (aryloxy)trimethylstannane with benzyl bromide giving aryl benzyl ether and bromotrimethylstannane. Bimolecular nucleophilic attack of the ary...

  已经对（芳氧基）三甲基锡烷与苄基溴反应生成芳基苄基醚和溴三甲基锡烷进行了动力学研究。原子的双分子亲核攻击...
• The Mechanism of the Reaction of (Aryloxy)trimethylstannane with Methanesulfonyl Chloride. Solvent and Substituent Effects on the Rate of the Reaction
  作者：Seizi Kozuka、Shigeru Yamaguchi、Waichiro Tagaki

  DOI：10.1246/bcsj.56.573

  日期：1983.2

  A kinetic study has been conducted on the reactions of (aryloxy)trimethylstannanes with methanesulfonyl chloride giving chlorotrimethylstannane and aryl methanesulfonates. The reaction was found to obey a second order kinetic equation. The solvent effect on the rate of the reaction appeared obscure although a small rate enhancement was observed in a polar solvent. Substituent effect of the aryloxyl

  对（芳氧基）三甲基锡烷与甲磺酰氯反应生成氯三甲基锡烷和甲磺酸芳基酯的反应进行了动力学研究。发现反应服从二级动力学方程。尽管在极性溶剂中观察到小的速率增强，溶剂对反应速率的影响似乎不明显。发现芳氧基的取代基效应取决于所使用的溶剂，同时观察到明显的等速关系。已建议该反应采用电荷分离的四中心过渡态。
• THE MECHANISM OF THE REACTION OF ARYLOXYTRIMETHYLSTANNANE WITH METHANESULFONYL CHLORIDE
  作者：Seizi Kozuka、Shigeru Yamaguchi、Waichiro Tagaki

  DOI：10.1246/cl.1981.1299

  日期：1981.9.5

  A kinetic study has been conducted for the reaction of aryloxytrimethylstannane with methanesulfonyl chloride. Substituent effect was found to be dependent on the solvent and obscure solvent effect was observed. A mechanism has been suggested involving nearly concerted four-center transition state.

  对芳氧基三甲基锡烷与甲磺酰氯的反应进行了动力学研究。发现取代基效应依赖于溶剂并且观察到不明显的溶剂效应。已经提出了一种涉及几乎一致的四中心过渡态的机制。