| 1330767-67-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1330767-67-3
• 化学式: C₁₄H₁₈O₆
• 分子量: 282.293
• InChiKey: FJNCSJRNRIHTPK-UHFFFAOYSA-N

物化性质

• 沸点：
  397.2±42.0 °C(Predicted)
• 密度：
  1.149±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

反应信息

• 作为反应物：
  描述：

  碘苯 、 在 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 18.0h， 以81%的产率得到diethyl 5-butyryl-4-phenylfuran-2,3-dicarboxylate
  参考文献：
  名称：

  Ruthenium-catalyzed coupling reaction of 2,3,5-trisubstituted furans with aryl halides through C–H bond cleavages

  摘要：

  A variety of functionalized furans were synthesized by way of a ruthenium-catalyzed coupling reaction of 2,3,5-trisubstituted furans with aryl halides through C-H bond cleavages. The feature of the reaction was facilitative preparation of furan derivatives good functional group tolerance. All reactions gave the desired products in moderate to good yields (56-89%) in the presences of [RuCl(2)(p-cymene)] and K(2)CO(3) in NMP at 120 degrees C. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.009