[Ag(1-ethynylcyclopentanol-H)]n | 1104018-58-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Ag(1-ethynylcyclopentanol-H)]n
• CAS: 1104018-58-7
• 化学式: C₇H₉AgO
• 分子量: 217.016
• InChiKey: CJZVFRVLJWCPEZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Au2(bis(diphenylphosphino)methane)2](PF6)2 、 [Ag(1-ethynylcyclopentanol-H)]n 以 甲醇 、 二氯甲烷 为溶剂， 以35%的产率得到[Ag6Au3(μ3-η(1)-1-ethynylcyclopentanol-H)6(μ-dppm)3](PF6)3
  参考文献：
  名称：

  Luminescent Au3Ag6 heterononanuclear complex of 1-ethynylcyclopentanol

  摘要：

  Reaction of polymeric species (AgC CC5H8OH)(n)(HC CC5H8OH = 1-ethynylcyclopentanol) with binuclear precursor [Au-2(mu-dppm)(2)](PF6)(2) (dppm = bis(diphenylphospnino)methane) caused isolation of Au3Ag6 heterononanuclear complex [Au3Ag6(mu-dppm)(3)(mu(3)-eta(1)-C CC5H8OH)(6)](PF6)(3). The Au3Ag6 (mu(3)-C CC5H8OH)(6) skeleton exhibits a hexagonal prismatic structure formed by mu(3)-eta(1)-C CC5H8OH bound to the Au3Ag6 cluster core. The compound is luminescent in both solid state and dichloromethane at both 298 and 77 K with the room temperature lifetimes in microsecond ranges, suggesting an emissive triplet parentage. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.07.010