5-(2,3-dihydro-indol-1-yl)cyclopent-1-enecarboxylic acid methyl ester | 1062573-54-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5-(2,3-dihydro-indol-1-yl)cyclopent-1-enecarboxylic acid methyl ester
• CAS: 1062573-54-9
• 化学式: C₁₅H₁₇NO₂
• 分子量: 243.305
• InChiKey: HMCPIWPLJGSOOD-AWEZNQCLSA-N

反应信息

• 作为产物：
  描述：

  Methyl 5-methoxycarbonyloxycyclopentene-1-carboxylate 、 吲哚啉 在 bis(η3-allyl-μ-chloropalladium(II)) N,O-双三甲硅基乙酰胺 作用下， 以 乙腈 为溶剂， 反应 24.17h， 生成 5-(2,3-dihydro-indol-1-yl)cyclopent-1-enecarboxylic acid methyl ester 、 5-(2,3-dihydro-indol-1-yl)cyclopent-1-enecarboxylic acid methyl ester
  参考文献：
  名称：

  Pd-catalyzed asymmetric allylic aminations with aromatic amine nucleophiles using chiral diaminophosphine oxides: DIAPHOXs

  摘要：

  Asymmetric allylic aminations with aromatic amine nucleophiles using Pd-DIAPHOX catalyst systems are described. The asymmetric allylic aminations of various allylic carbonates proceeded using 2-5 mol % of the catalyst and BSA, providing the corresponding N-aryl chiral allylic amines in up to 99% ee for cyclic substrates, and in up to 97% ee for acyclic substrates. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2008.07.015