[(3R,4R,1'S)-2-Eth-(Z)-ylidene-4-hydroxymethyl-1',3',3'-trimethyl-bicyclohexyl-6-en-3-yl]-methanol | 117894-17-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(3R,4R,1'S)-2-Eth-(Z)-ylidene-4-hydroxymethyl-1',3',3'-trimethyl-bicyclohexyl-6-en-3-yl]-methanol
• CAS: 117894-17-4
• 化学式: C₁₉H₃₂O₂
• 分子量: 292.462
• InChiKey: SNSZBOYRNQFTSV-UODHKRAUSA-N

反应信息

• 作为产物：
  描述：

  Acetic acid (1S,3aR,7aR)-7-eth-(Z)-ylidene-3-oxo-6-((S)-1,3,3-trimethyl-cyclohexyl)-1,3,3a,4,7,7a-hexahydro-isobenzofuran-1-yl ester 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 0.17h， 以3 mg的产率得到[(3R,4R,1'S)-2-Eth-(Z)-ylidene-4-hydroxymethyl-1',3',3'-trimethyl-bicyclohexyl-6-en-3-yl]-methanol
  参考文献：
  名称：

  Mayol, Luciano; Piccialli, Vincenzo; Sica, Donato, Gazzetta Chimica Italiana, 1988, vol. 118, # 8, p. 559 - 564

  摘要：

  DOI：

文献信息

• Metabolites from the marine sponge . Three further nor-diterpenes, one of them based on a novel carbocyclic skeleton.
  作者：Luciano Mayol、Vincenzo Piccialli、Donato Sica

  DOI：10.1016/s0040-4020(01)82087-1

  日期：1986.1

  isolated from the Mediterranean sponge and their structures have been determined by spectroscopic and chemical evidences. The structures of two of the new metabolites ( and ) are strictly related to gracilin A (), a previously isolated nor-diterpene from the same source, whereas the third compound, spongionellin (), possesses a new carbocyclic skeleton. The biogenesis of nor-diterpenes from is briefly

  从地中海海绵中分离出三个新的非二萜，其结构已通过光谱和化学证据确定。两个新的代谢产物（和）的结构与gracilin A（）严格相关，gracilin A（）是先前从同一来源分离的去二萜，而第三个化合物spongionellin（）具有新的碳环骨架。简要讨论了正二萜的生物发生。