p-tetraformylcalix[4]arene tetradodecyl ether | 1221971-87-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: p-tetraformylcalix[4]arene tetradodecyl ether
• CAS: 1221971-87-4
• 化学式: C₈₀H₁₂₀O₈
• 分子量: 1209.83
• InChiKey: UQLZXFXURPHVRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.81
• 重原子数：
  88.0
• 可旋转键数：
  52.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  105.2
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  p-tetraformylcalix[4]arene tetradodecyl ether 在 sodium chlorite 、 氨基磺酸 作用下， 以 氯仿 、 水 、 丙酮 为溶剂， 以94%的产率得到p-tetracarboxycalix[4]arene tetradodecyl ether
  参考文献：
  名称：

  Self-Organized Honeycomb-Patterned Microporous Polystyrene Thin Films Fabricated by Calix[4]arene Derivatives

  摘要：

  Calix[4]arene derivatives bearing carboxyl groups at the upper rim and alkyl groups at the lower rim were synthesized. Micrometer-size porous honeycomb-patterned thin films were prepared by evaporating chloroform solution of polystyrene containing the calixarene derivatives under high humidity. These films were coated on gold electrodes of QCM, and the high-frequency changes were observed to detect volatile organic compounds such as dichlorobenzene.

  DOI：

  10.1021/la100434b
• 作为产物：
  描述：

  杯[4]芳烃 在 sodium hydride 、 三氟乙酸 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 39.17h， 生成 p-tetraformylcalix[4]arene tetradodecyl ether
  参考文献：
  名称：

  Self-Organized Honeycomb-Patterned Microporous Polystyrene Thin Films Fabricated by Calix[4]arene Derivatives

  摘要：

  Calix[4]arene derivatives bearing carboxyl groups at the upper rim and alkyl groups at the lower rim were synthesized. Micrometer-size porous honeycomb-patterned thin films were prepared by evaporating chloroform solution of polystyrene containing the calixarene derivatives under high humidity. These films were coated on gold electrodes of QCM, and the high-frequency changes were observed to detect volatile organic compounds such as dichlorobenzene.

  DOI：

  10.1021/la100434b