1-(10-(acryloyloxy)decyl)-3-methylimidazolium chloride | 948016-47-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-(10-(acryloyloxy)decyl)-3-methylimidazolium chloride
• 英文别名: 10-(3-methylimidazol-3-ium-1-yl)decyl prop-2-enoate;chloride
• CAS: 948016-47-5
• 化学式: C₁₇H₂₉N₂O₂*Cl
• 分子量: 328.882
• InChiKey: VVLGGYVRJYIECJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.17
• 重原子数：
  22
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  35.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 10-chlorodecyl acrylate 反应 24.0h， 以26%的产率得到1-(10-(acryloyloxy)decyl)-3-methylimidazolium chloride
  参考文献：
  名称：

  Formation of a Liquid-Crystalline Interpenetrating Poly(ionic liquid) Network Hydrogel

  摘要：

  Preparation of a liquid-crystalline ionic-liquid (IL)-based interpenetrating polymer network (IPN) is described. The IPN is prepared sequentially by first photopolymerizing a self-assembled aqueous mixture of an IL monomer (1-(10-(acryloyloxy)decyl)-3-methylimidazolium chloride) that possesses an acryloyl moiety at the terminus of a C-10 alkyl chain of the IL cation. In the second step, an acrylate counteranion is introduced and then photopolymerized to yield a durable self-supporting network polymer. Thermal analysis indicates the formation of a homogeneous (well-blended constituent polymers) IPN. The IPN adopts a lamellar structure possessing some residual in-plane tetragonal perforations, as evidenced by small-angle X.-ray scattering (SAXS). The IPN can absorb large quantities of water, swelling to nearly 60 times its original volume, but retains mechanical integrity making it a durable hydrogel.

  DOI：

  10.1021/ma102146r