1-[4-[[3-[(4-Prop-2-ynoylphenoxy)methyl]phenyl]methoxy]phenyl]prop-2-yn-1-one | 1413282-65-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-[4-[[3-[(4-Prop-2-ynoylphenoxy)methyl]phenyl]methoxy]phenyl]prop-2-yn-1-one
• CAS: 1413282-65-1
• 化学式: C₂₆H₁₈O₄
• 分子量: 394.427
• InChiKey: NFSCKNOTFCOWNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  间苯三酚 、 1-[4-[[3-[(4-Prop-2-ynoylphenoxy)methyl]phenyl]methoxy]phenyl]prop-2-yn-1-one 在 hexafluorophosphoric acid 、 溶剂黄146 作用下， 以 水 为溶剂， 反应 48.0h， 以92%的产率得到
  参考文献：
  名称：

  Four-Step Route to Novel Bisflavylium Dications - First Synthesis of Phloroglucinol-Type Derivatives

  摘要：

  Various bisflavylium dications have been prepared in an efficient four-step manner utilizing the acid-mediated condensation between bis(arylethynylketones) and activated phenols as the key step. Of special note is that phloroglucinol-type bisflavylium salts have been obtained for the first time thanks to this procedure.

  DOI：

  10.1055/s-0032-1316681
• 作为产物：
  描述：

  在 2-碘酰基苯甲酸 作用下， 以 乙酸乙酯 为溶剂， 反应 12.0h， 以99%的产率得到1-[4-[[3-[(4-Prop-2-ynoylphenoxy)methyl]phenyl]methoxy]phenyl]prop-2-yn-1-one
  参考文献：
  名称：

  Four-Step Route to Novel Bisflavylium Dications - First Synthesis of Phloroglucinol-Type Derivatives

  摘要：

  Various bisflavylium dications have been prepared in an efficient four-step manner utilizing the acid-mediated condensation between bis(arylethynylketones) and activated phenols as the key step. Of special note is that phloroglucinol-type bisflavylium salts have been obtained for the first time thanks to this procedure.

  DOI：

  10.1055/s-0032-1316681

文献信息

• MODIFIED TRIAROYLBENZENE-SKELETON POLYMER
  申请人：Oda Takuro

  公开号：US20110319551A1

  公开（公告）日：2011-12-29

  It is an object to provide a film having both high transparency and high heat resistance, and particularly a coating solution for forming a coating film from which an optical film can be produced. A triaroylbenzene-skeleton polymer in which a terminal of a polymer produced by polymerizing a compound of Formula [1] below is modified by a compound of Formula [2] below. A coating solution for forming a coating film, comprising the polymer. A film obtained from the coating solution for forming a coating film. In the formulae below, X 1 is a divalent group of Formula [1a], Formula [1b], or Formula [1c] below (where Y 1 and Y 2 are independently a C 1-2 alkylene group; n is an integer of 1 to 6; and m is an integer of 1 to 6), X 2 is divalent benzene, thiophene, furan, or fluorine, and X 3 is a hydrogen atom, a halogen atom, CF 3 , a C 1-6 alkoxy group, or a C 1-6 alkyl group.
• US8455590B2
  申请人：——

  公开号：US8455590B2

  公开（公告）日：2013-06-04
• Four-Step Route to Novel Bisflavylium Dications - First Synthesis of Phloroglucinol-Type Derivatives
  作者：Marie Kueny-Stotz、Stefan Chassaing、Raymond Brouillard

  DOI：10.1055/s-0032-1316681

  日期：2012.9

  Various bisflavylium dications have been prepared in an efficient four-step manner utilizing the acid-mediated condensation between bis(arylethynylketones) and activated phenols as the key step. Of special note is that phloroglucinol-type bisflavylium salts have been obtained for the first time thanks to this procedure.