8,8-dibutyl-7,9-dioxa-8-stannaspiro[4.5]dec-2-ene | 284684-89-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 8,8-dibutyl-7,9-dioxa-8-stannaspiro[4.5]dec-2-ene
• CAS: 284684-89-5
• 化学式: C₁₅H₂₈O₂Sn
• 分子量: 359.096
• InChiKey: KGOGBYLTWMAXIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.41
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  8,8-dibutyl-7,9-dioxa-8-stannaspiro[4.5]dec-2-ene 、 5,5-diethyl-1,3-dioxane-2-thione 、 在 乙醚 、 crude material 、 silica gel 、 ethyl ether hexanes 作用下， 反应 24.33h， 以The desired 11,11-diethyl-7,9,13,14-tetraoxadispiro[4.2.5.2]pentadec-1-ene (DECP 5) was obtained as white solid in 72% yield的产率得到11,11-diethyl-7,9,13,14-tetraoxadispiro[4.2.5.2]pentadec-1-ene
  参考文献：
  名称：

  Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates

  摘要：

  提供了光聚合组成物，其为乙烯醚、含有碘离子盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组成物还可以包括环氧化合物、多元醇、螺环正噻碳酸酯。本发明的一种实施例是由乙烯醚、螺环正噻碳酸酯和光引发剂体系组成的可聚合组成物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的可聚合组成物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正噻碳酸酯和光引发剂体系组成的可聚合组成物。此外，本发明的另一种实施例是某些新型螺环正噻碳酸酯化合物。这些新型螺环正噻碳酸酯化合物中至少包括一个环氧基团作为取代基。

  公开号：

  US06458865B2

文献信息

• PHOTOPOLYMERIZABLE VINYL ETHER BASED MONOMERIC FORMULATIONS AND POLYMERIZABLE COMPOSITIONS WHICH MAY INCLUDE CERTAIN NOVEL SPIROORTHOCARBONATES
  申请人：——

  公开号：US20020013380A1

  公开（公告）日：2002-01-31

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组合物，其为乙烯醚、包括碘化物盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化合物、多元醇、螺环正交碳酸酯。本发明的一种实施例是由乙烯醚、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施例是某些新型螺环正交碳酸酯化合物。这些新型螺环正交碳酸酯化合物中，每个化合物都包括至少一个环氧基团作为取代基。
• Novel spiroorthocarbonates
  申请人：The Curators of the University of Missouri

  公开号：US20030119931A1

  公开（公告）日：2003-06-26

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光固化组合物，它们是乙烯醚、包含碘鎓盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化物、多元醇、螺内酯碳酸酯。本发明的一种实施方式是由乙烯醚、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施方式是一些新型螺内酯碳酸酯化合物。这些新型螺内酯碳酸酯化合物中的每一种都包括至少一个环氧基团作为取代基。
• Spiroorthocarbonates containing epoxy groups
  申请人：Curators of the University of Missouri

  公开号：US06653486B2

  公开（公告）日：2003-11-25

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组合物，其是乙烯醚、含碘盐的光引发剂体系、可见光敏化剂和电子给体化合物的反应产物。这些单体/低聚物组合物还可以包括环氧化合物、多元醇、螺环正碳酸酯。本发明的一种实施例是由乙烯醚、螺环正碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施例是某些新型螺环正碳酸酯化合物。这些新型螺环正碳酸酯化合物中，每个都包括至少一个环氧基团作为取代基。