diethyl (2-(10H-phenothiazin-10-yl)ethyl)phosphonate | 32497-74-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: diethyl (2-(10H-phenothiazin-10-yl)ethyl)phosphonate
• 英文别名: (2-phenothiazin-10-yl-ethyl)-phosphonic acid diethyl ester；10-(2-Diethoxyphosphorylethyl)phenothiazine；10-(2-diethoxyphosphorylethyl)phenothiazine
• CAS: 32497-74-8
• 化学式: C₁₈H₂₂NO₃PS
• 分子量: 363.417
• InChiKey: WVWKRLMACFETHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.56
• 重原子数：
  24.0
• 可旋转键数：
  7.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  38.77
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  diethyl (2-(10H-phenothiazin-10-yl)ethyl)phosphonate 在 三甲基溴硅烷 、 水 作用下， 以 1,4-二氧六环 、 甲醇 为溶剂， 以62 %的产率得到2-Phenothiazin-10-ylethylphosphonic acid
  参考文献：
  名称：

  CONDUCTIVE SUBSTRATE, PEROVSKITE SUBSTRATE USING THE CONDUCTIVE SUBSTRATE AND SOLAR CELL USING THE PEROVSKITE SUBSTRATE

  摘要：

  The present invention discloses a conductive substrate, a perovskite substrate using the conductive substrate, and a solar cell using the perovskite substrate. The conductive substrate, the perovskite substrate, and the solar cell of the present invention include a conductive base and a conductive compound stacked on the conductive base. The conductive compound is represented by Formula 1, 2 or 3. The conductive compound is capable of multi-electron redox reactions, possesses p-type organic molecular properties, and has an oxidation potential or highest occupied molecular orbital (HOMO) matching the valence band of perovskite so that holes generated in an absorber layer are selectively separated for the application of the perovskite material, achieving enhanced photoelectric conversion efficiency of the solar cell and a significantly reduced difference between the forward and reverse conversion efficiencies (hysteresis index) of the solar cell.

  公开号：

  US20240188428A1
• 作为产物：
  描述：

  吩噻嗪 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 26.0h， 生成 diethyl (2-(10H-phenothiazin-10-yl)ethyl)phosphonate
  参考文献：
  名称：

  CONDUCTIVE SUBSTRATE, PEROVSKITE SUBSTRATE USING THE CONDUCTIVE SUBSTRATE AND SOLAR CELL USING THE PEROVSKITE SUBSTRATE

  摘要：

  The present invention discloses a conductive substrate, a perovskite substrate using the conductive substrate, and a solar cell using the perovskite substrate. The conductive substrate, the perovskite substrate, and the solar cell of the present invention include a conductive base and a conductive compound stacked on the conductive base. The conductive compound is represented by Formula 1, 2 or 3. The conductive compound is capable of multi-electron redox reactions, possesses p-type organic molecular properties, and has an oxidation potential or highest occupied molecular orbital (HOMO) matching the valence band of perovskite so that holes generated in an absorber layer are selectively separated for the application of the perovskite material, achieving enhanced photoelectric conversion efficiency of the solar cell and a significantly reduced difference between the forward and reverse conversion efficiencies (hysteresis index) of the solar cell.

  公开号：

  US20240188428A1

文献信息

• Petrov,K.A. et al., Journal of general chemistry of the USSR, 1971, vol. 41, p. 105 - 109
  作者：Petrov,K.A. et al.

  DOI：——

  日期：——