| 1161933-77-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1161933-77-2
• 化学式: C₁₂₈H₁₀₈N₆O₁₆
• 分子量: 1986.3
• InChiKey: FNSWLPMZJPZRJQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 在 zinc(II) acetate dihydrate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 29.0h， 以0.001 g的产率得到
  参考文献：
  名称：

  Toward an n-Type Molecular Wire: Electron Hopping within Linearly Linked Perylenediimide Oligomers

  摘要：

  A series of linearly linked perylenediimide (PDI) dimers and trimers were synthesized in which the PDI pi systems are nearly orthogonal. These oligomers and several model compounds were singly reduced, and intramolecular electron hopping between the PDI molecules was probed by electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) spectroscopy. When the functional groups attached to the ends of the oligomers were chosen to make each PDI molecule electronically equivalent, the single electron hops between the PDI molecules with rates that significantly exceed 10(7) s(-1). Rapid electron hopping between pairs of PDI molecules having orthogonal pi systems is unexpected and may expand the possible design motifs for organic electronic materials based on PDI.

  DOI：

  10.1021/ja902258g