Methyl (E,5R,2S,6S)-5,6-O-isopropylidene-7-<(methylsulfonyl)oxy>-2-methyl-3-heptenoate | 121012-30-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Methyl (E,5R,2S,6S)-5,6-O-isopropylidene-7-<(methylsulfonyl)oxy>-2-methyl-3-heptenoate
• CAS: 121012-30-4
• 化学式: C₁₃H₂₂O₇S
• 分子量: 322.379
• InChiKey: HLNGGISTTAYRDV-OANNRXPXSA-N

反应信息

• 作为产物：
  描述：

  甲基锂 、 (E)-(S)-4-Methanesulfonyloxy-4-((4S,5S)-5-methanesulfonyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-2-enoic acid methyl ester 在 三氟化硼乙醚 、 lithium bromide 作用下， 生成 Methyl (E,5R,2S,6S)-5,6-O-isopropylidene-7-<(methylsulfonyl)oxy>-2-methyl-3-heptenoate
  参考文献：
  名称：

  Very high chemoselective, regioselective, and E-stereoselective 1,3-chirality transfer involving reaction of acyclic (E)- and (Z)-.gamma.-mesyloxy .alpha.,.beta.-enoates and organocyanocopper-trifluoroborane reagents. Efficient synthetic routes to functionalized chiral .alpha.-alkyl (E)-.beta.,.gamma.-enoates and (E)-allylic alcohols with high optical purity

  摘要：

  DOI：

  10.1021/ja00195a045