[(acac)2Ru(III)(μ-3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine)Ru(III)(acac)2](2+) | 774198-42-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(acac)2Ru(III)(μ-3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine)Ru(III)(acac)2](2+)
• CAS: 774198-42-4
• 化学式: C₃₂H₄₂N₈O₈Ru₂
• 分子量: 868.874
• InChiKey: CUQYOCQOHOSXSY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(acac)2Ru(II)(μ-3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine)Ru(III)(acac)2](1+) 在 Bu₄NPF₆ 作用下， 以 二氯甲烷 为溶剂， 生成 [(acac)2Ru(III)(μ-3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine)Ru(III)(acac)2](2+)
  参考文献：
  名称：

  Isovalent and Mixed-Valent Diruthenium Complexes [(acac)₂Ru^II (μ-bpytz)Ru^II(acac)₂] and [(acac)₂Ru^II(μ-bpytz)Ru^III(acac)₂](ClO₄) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine):  Synthesis, Spectroelectrochemical, and EPR Investigation

  摘要：

  The title compounds involving the structurally characterized bridging ligand bpytz were characterized, showing very strong electrochemical stabilization of the mixed-valent (RuRuIII)-Ru-II state (K-c = 10(13.9)) but no detectable (epsilon < 20 M-1 cm(-1)) intervalence charge-transfer band in the infrared region. In situ reduction of the neutral precursor produces a diruthenium(II) complex of the bpytz radical anion according to EPR spectroscopy, whereas oxidation of the mixed-valent form leads to a diruthenium(III) species.

  DOI：

  10.1021/ic049346r