[Ru(2-(4-chlorophenylazo)aniline)(2,2',6',2''-terpyridine)]ClO4 | 1204403-02-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Ru(2-(4-chlorophenylazo)aniline)(2,2',6',2''-terpyridine)]ClO4
• 英文别名: [Ru(2-(4-chlorophenylazo)aniline)(tpy)]ClO4
• CAS: 1204403-02-0
• 化学式: C₂₇H₂₀ClN₆Ru*ClO₄
• 分子量: 664.47
• InChiKey: SCANBKYUYFFQDS-PHWSNXGDSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  α,α,α-三联吡啶 以 甲醇 为溶剂， 生成 [Ru(2-(4-chlorophenylazo)aniline)(2,2',6',2''-terpyridine)]ClO4
  参考文献：
  名称：

  Syntheses and properties of new metal–carbon bonded heteroleptic complexes of ruthenium(II) containing terpyridine coligand

  摘要：

  Reactions of 2-(arylazo) aniline, HL [H represents the dissociable protons upon orthometallation and HL is p-RC6H4N = NC6H4-NH2; R = H for HL1; CH3 for HL2 and Cl for HL3] with Ru(R-1-tpy)Cl-3 (where R-1-tpy is 4'-(R-1)-2,2',6 '',2 ''-terpyridine and R-1 = H or 4-N, N-dimethylaminophenyl or 4-methylphenyl) afford a group of complexes of type [Ru(L)(R-1-tpy)]center dot ClO4 each of which contains C, N, N coordinated L-as a tridentate ligand along with a terpyridine. Structure of one such complex has been determined by X-ray crystallography. All the Ru(II) complexes are diamagnetic, display characteristic H-1 NMR signals and intense d pi(Ru-II) -> pi*(tpy) MLCT transitions in the visible region. Cyclic voltammetric studies on [Ru(L)(R-1-tpy)]center dot ClO4 complexes show Ru(II)-Ru(III) oxidation within 0.63-0.67 V versus SCE. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.024