3,3'-(2,3,6,7-tetrapentylanthracene-9,10-diyl)bis(prop-2-yn-1-ol) | 1186589-80-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3,3'-(2,3,6,7-tetrapentylanthracene-9,10-diyl)bis(prop-2-yn-1-ol)
• CAS: 1186589-80-9
• 化学式: C₄₀H₅₄O₂
• 分子量: 566.868
• InChiKey: OQOVOKAUIRLGPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.61
• 重原子数：
  42.0
• 可旋转键数：
  16.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  40.46
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4-(4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)benzoic acid 、 3,3'-(2,3,6,7-tetrapentylanthracene-9,10-diyl)bis(prop-2-yn-1-ol) 在 偶氮二甲酸二异丙酯 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 以21%的产率得到
  参考文献：
  名称：

  Polymeric Ladderphanes

  摘要：

  A new class of polymers, which have a double-stranded polybinorbornene skeleton with multilayer planar oligoaryl linkers, defined as polymeric ladderphanes, are synthesized. The structures of these ladderphanes are determined by spectroscopic means. Photophysical studies and time-resolved fluorescence spectroscopic investigations reveal that there is a strong interaction between the chromophore linkers. Thus, Sorel band splitting in the absorption spectrum of the polymer with porphyrin linker (12e), significant fluorescence quenching with oligoaryl linkers (12b-d), and excimer emission with a terphenylene-diethynylene linker (12a) are characteristic photophysical properties of these polymers. Scanning tunneling microscopy shows that polymers 12b and d exhibit a ladder-like morphology and form a supramolecular assembly leading to a two-dimensional ordered array on a highly oriented pyrolytic graphite surface.

  DOI：

  10.1021/ja9035362
• 作为产物：
  描述：

  叔丁基二甲基(2-丙炔氧基)硅烷 、 2,3,6,7-tetra-n-pentyl-9,10-anthraquinone 在 正丁基锂 、 tin(ll) chloride 、 四丁基氟化铵 作用下， 以 四氢呋喃 、 正己烷 、 水 、 溶剂黄146 为溶剂， 反应 36.0h， 以40%的产率得到3,3'-(2,3,6,7-tetrapentylanthracene-9,10-diyl)bis(prop-2-yn-1-ol)
  参考文献：
  名称：

  Polymeric Ladderphanes

  摘要：

  A new class of polymers, which have a double-stranded polybinorbornene skeleton with multilayer planar oligoaryl linkers, defined as polymeric ladderphanes, are synthesized. The structures of these ladderphanes are determined by spectroscopic means. Photophysical studies and time-resolved fluorescence spectroscopic investigations reveal that there is a strong interaction between the chromophore linkers. Thus, Sorel band splitting in the absorption spectrum of the polymer with porphyrin linker (12e), significant fluorescence quenching with oligoaryl linkers (12b-d), and excimer emission with a terphenylene-diethynylene linker (12a) are characteristic photophysical properties of these polymers. Scanning tunneling microscopy shows that polymers 12b and d exhibit a ladder-like morphology and form a supramolecular assembly leading to a two-dimensional ordered array on a highly oriented pyrolytic graphite surface.

  DOI：

  10.1021/ja9035362