2,3,6,7-tetra-n-pentyl-9,10-anthraquinone | 113568-81-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3,6,7-tetra-n-pentyl-9,10-anthraquinone
• 英文别名: 2,3,6,7-Tetrapentylanthracene-9,10-dione
• CAS: 113568-81-3
• 化学式: C₃₄H₄₈O₂
• 分子量: 488.754
• InChiKey: DMEVQOMESOOGHB-UHFFFAOYSA-N

物化性质

• 熔点：
  103 °C(Solv: ethanol (64-17-5))
• 沸点：
  615.1±55.0 °C(Predicted)
• 密度：
  1.000±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.6
• 重原子数：
  36
• 可旋转键数：
  16
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3,6,7-tetra-n-pentyl-9,10-anthraquinone 在 Al(c-C6H11O)3 作用下， 反应 48.0h， 以81%的产率得到2,3,6,7-tetra-n-pentylanthracene
  参考文献：
  名称：

  Bender, Dietmar; Mueller, Klaus, Chemische Berichte, 1988, vol. 121, p. 1187 - 1198

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4,5,8,4a,8a,9a,10a-octahydro-2,3,6,7-tetra-n-pentyl-9,10-anthraquinone 在 氢氧化钾 、 氧气 作用下， 以 乙醇 为溶剂， 以64%的产率得到2,3,6,7-tetra-n-pentyl-9,10-anthraquinone
  参考文献：
  名称：

  Bender, Dietmar; Mueller, Klaus, Chemische Berichte, 1988, vol. 121, p. 1187 - 1198

  摘要：

  DOI：

文献信息

• Original synthesis of tetraalkylquinones by poly-SRN1 reactions
  作者：Patrice Vanelle、Thierry Terme、Michel P Crozet

  DOI：10.1016/s0040-4039(00)01069-8

  日期：2000.8

  A series of complex and highly branched quinones were obtained by reacting an original tetraalkylating agent, 2,3,5,6-tetrachloromethyl-1,4-benzoquinone with primary or secondary nitroalkanes under S(RN)1 reactions conditions. (C) 2000 Elsevier Science Ltd. All rights reserved.
• Polymeric Ladderphanes
  作者：Chih-Ming Chou、Shern-Long Lee、Chih-Hsien Chen、Akkattu Thankappan Biju、Hsian-Wen Wang、Yi-Lin Wu、Guo-Fu Zhang、Kuang-Wei Yang、Tsong-Shin Lim、Min-Jie Huang、Po-Yu Tsai、Kin-Chuan Lin、Shou-Ling Huang、Chun-hsien Chen、Tien-Yau Luh

  DOI：10.1021/ja9035362

  日期：2009.9.9

  A new class of polymers, which have a double-stranded polybinorbornene skeleton with multilayer planar oligoaryl linkers, defined as polymeric ladderphanes, are synthesized. The structures of these ladderphanes are determined by spectroscopic means. Photophysical studies and time-resolved fluorescence spectroscopic investigations reveal that there is a strong interaction between the chromophore linkers. Thus, Sorel band splitting in the absorption spectrum of the polymer with porphyrin linker (12e), significant fluorescence quenching with oligoaryl linkers (12b-d), and excimer emission with a terphenylene-diethynylene linker (12a) are characteristic photophysical properties of these polymers. Scanning tunneling microscopy shows that polymers 12b and d exhibit a ladder-like morphology and form a supramolecular assembly leading to a two-dimensional ordered array on a highly oriented pyrolytic graphite surface.
• BENDER, DIETMAR;MULLEN, KLAUS, CHEM. BER., 121,(1988) N 6, 1187-1197
  作者：BENDER, DIETMAR、MULLEN, KLAUS

  DOI：——

  日期：——