[Pt(bis(diphenylphosphino)methane)(OTf)2] | 136569-56-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [Pt(bis(diphenylphosphino)methane)(OTf)2]
• 英文别名: [Pt(bis(diphenylphosphino)methane)(OTf)₂]；[Pt(dppm)(OTf)₂]；[Pt(bis(diphenylphosphino)methane)(triflato)2]；[Pt2(bis(diphenylphosphino)methane)(CF3SO3)2]；[Pt(dppm)(OTf)2]
• CAS: 136569-56-7
• 化学式: C₂₇H₂₂F₆O₆P₂PtS₂
• 分子量: 877.618
• InChiKey: HWPQCONXLLYKRO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.84
• 重原子数：
  44.0
• 可旋转键数：
  8.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  86.74
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  [Pt(bis(diphenylphosphino)methane)(OTf)2] 、 cyclopentadienylthallium(I) 以 二氯甲烷 为溶剂， 以90%的产率得到{(η5-cyclopentadienyl)(dppm)platinum} triflate
  参考文献：
  名称：

  Fallis, Stephen; Rodriguez, Lori; Anderson, Gordon K., Organometallics, 1993, vol. 12, # 10, p. 3851 - 3855

  摘要：

  DOI：
• 作为产物：
  描述：

  dichloro(bis(diphenylphosphino)methane)platinum(II) 、 silver trifluoromethanesulfonate 以 二氯甲烷 、 乙腈 为溶剂， 生成 [Pt(bis(diphenylphosphino)methane)(OTf)2]
  参考文献：
  名称：

  Regioselective Double Cycloplatination of 9,10-Bis(diphenylphosphino)anthracene

  摘要：

  Double cyclometalation of 9,10-bis(diphenylphosphino)anthracene (PAnP) by Pt(L)(OTf)(2) (L = diphosphines, OTf = CF3SO3) gives rise to the geometrical isomers syn- and anti-[Pt-2(L)(2)(PAnP-H-2)](OTf)(2) (Pt-2). The reaction is regioselective, with the syn-isomer being the kinetic product. The cyclomelation is reversible, and thermodynamic product distribution is obtained after prolonged standing. The ratio of the isomers is subject to the influence of solvents and ancillary diphosphines. Protonolysis of the Pt-C leads to a monocyclometalated intermediate. A mechanistic postulate that invokes a preferential electrophilic attack of the Pt ions at the C-H bonds of the anthracenyl ring is proposed to explain the regioselectivity.

  DOI：

  10.1021/om800356k
• 作为试剂：
  描述：

  丙炔酸乙酯 、 均三甲苯 在 [Pt(bis(diphenylphosphino)methane)(OTf)2] 、 三氟乙酸 作用下， 反应 5.0h， 以31%的产率得到diethyl (1E,3Z)-4-(2,4,6-trimethylphenyl)buta-1,3-diene-1,3-dicarboxylate
  参考文献：
  名称：

  Regio- and Stereocontrolled Reaction of Arenes with Ethyl Propiolate Catalyzed by Palladium or Platinum Complexes with a Bidentate Phosphine Ligand. An Efficient and Straightforward Synthesis of (1Z,3E)-1-Aryl-1,3-butadienes

  摘要：

  在30°C下，使用[Pd(dppe)(OAc)2]催化剂，在TFA中，间三甲苯与乙基丙二酸乙酯反应5小时，选择性地生成了二乙基(2E,4Z)-4-[(2,4,6-三甲基苯基)亚甲基]-2-戊二烯二酸酯。筛选多种双齿膦配体表明，dppe和dppm配体有利于芳基丁二烯的形成。此反应应用于其他富电子芳烃，发现对于芳基丁二烯和扩展π共轭分子的合成是有效的。通过NMR和单晶X射线结构分析确认了芳烃对丙二酸酯的区域和立体选择性加成，表明芳基丁二烯的形成包括芳烃和一个金属对乙基丙二酸酯三键的反式加成，随后对另一分子乙基丙二酸酯进行顺式加成。类似地，使用[Pt(dppe)(OTf)2]催化剂，在多种芳烃与乙基丙二酸酯的反应中，选择性地生成了芳基丁二烯。在Pd或Pt催化的芳烃与乙基丙二酸酯反应中，发现双齿配体控制了反应，引导芳基丁二烯的形成。

  DOI：

  10.1246/bcsj.20120233

文献信息

• Photoluminescent macrocyclic Pd(II) and Pt(II) dimeric complexes with Ph2P–CC–PPh2 spacer
  作者：Dengfeng Xu、Hunter J Murfee、Wytze E van der Veer、Bo Hong

  DOI：10.1016/s0022-328x(99)00538-0

  日期：2000.2

  The synthesis and characterization of macrocyclic Pd(II)/Pt(II) dimers and their monomeric precursors with diphosphine spacer Ph2P-C=C-PPh2 (C2P2) are reported. Their excited-state properties, including solvent-dependent absorption, emission and quantum yield, are studied. When the solvent polarity increases, solvatochromic absorption band shifts to higher energy, emission maximum shifts to lower energy, and quantum yield decreases. In addition, the host-guest behavior of these new inorganic macrocycles is also reported here. (C) 2000 Elsevier Science S.A. All rights reserved.
• Synthesis and Electronic Spectroscopy of Luminescent Cyclometalated Platinum−Anthracenyl Complexes
  作者：Jian Hu、Ronger Lin、John H. K. Yip、Kwok-Yin Wong、Dik-Lung Ma、Jagadese J. Vittal

  DOI：10.1021/om700706r

  日期：2007.12.1

  Dicyclometalated complexes syn- and anti-[Pt-2(L)(2)(PAnP-H-2)](OTf)(2) (Pt-2) are synthesized from reactions of 9,10-bis(diphenylphosphino)anthracene (PAnP) and Pt(L)(OTf)(2) (L = diphosphines, OTf = CF3SO3). Because of metal perturbation on the electronic structure of the anthracenyl ring, the B-1(2u)- <- (1)A(g) transition, which is forbidden in anthracene, is observed in the electronic spectra of Pt-2. The complexes display fluorescence arising from the ligand-centered S-1 excited state. No significant heavy atom effect is observed in the Pt-2 complexes. To understand the effect of the number of Pt ions on the extent of perturbation, a mononuclear analogue, [Pt(dppe)(PAn-H)]ClO4 (PAn = 9-diphenylphosphinoanthracene), is prepared and its spectroscopy studied.