1-(3-acetylphenyl)pentyl nitrate | 1332887-33-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(3-acetylphenyl)pentyl nitrate
• CAS: 1332887-33-8
• 化学式: C₁₃H₁₇NO₄
• 分子量: 251.282
• InChiKey: PSRKZXFHSIXPGC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-acetyl-3-pentylbenzene 在 N-羟基邻苯二甲酰亚胺 、 ammonium cerium (IV) nitrate 作用下， 以 乙腈 为溶剂， 以80%的产率得到1-(3-acetylphenyl)pentyl nitrate
  参考文献：
  名称：

  Direct oxidative installation of nitrooxy group at benzylic positions and its transformation into various functionalities

  摘要：

  C-H Nitrooxylation at benzylic positions has been achieved by employing the N-hydroxyphthalimide (NHPI) catalyst/cerium(IV) ammonium nitrate (CAN) reagent system. The nitrooxy groups were demonstrated to function as tentative hydroxy protecting groups, as well as excellent leaving groups for N- and C-substitution reactions. Hence, the present method offers a unique way to synthesize diverse O-. N-, or C-functionalized benzylic compounds from simple alkyl aromatics. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.06.118