2-methyl-3-(methylsulfonyl)-N-(1-methyl-1H-tetrazol-5-yl)-4-(trifluoromethyl)benzamide | 1361134-48-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-methyl-3-(methylsulfonyl)-N-(1-methyl-1H-tetrazol-5-yl)-4-(trifluoromethyl)benzamide
• 英文别名: 2-methyl-3-methylsulfonyl-N-(1-methyltetrazol-5-yl)-4-(trifluoromethyl)benzamide
• CAS: 1361134-48-6
• 化学式: C₁₂H₁₂F₃N₅O₃S
• 分子量: 363.32
• InChiKey: KNJZLEGWAJKFKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  115
• 氢给体数：
  1
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  2-methyl-3-(methylsulfonyl)-N-(1-methyl-1H-tetrazol-5-yl)-4-(trifluoromethyl)benzamide 、 碘乙烷 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以26%的产率得到N-ethyl-2-methyl-3-(methylsulfonyl)-N-(1-methyl-1H-tetrazol-5-yl)-4-(trifluoromethyl)benzamide
  参考文献：
  名称：

  N-(1,2,5-OXADIAZOL-3-YL)-, N-(1,3,4-OXADIAZOL-2-YL)-, N-(TETRAZOL-5-YL)-, AND N-(TRIAZOL-5-YL) ARYL CARBOXYLIC ACID AMIDES AND USE THEREOF AS HERBICIDES

  摘要：

  通式（I）中的N-(1,2,5-噁二唑-3-基)-、N-(1,3,4-噁二唑-2-基)-、N-(四唑-5-基)-或N-(三唑-5-基)芳基羧酰胺被描述为除草剂。在该式（I）中，R、V、X、Y和Z是氢、有机基团如烷基或其他基团如卤素等基团。Q是四唑基、三唑基或噁二唑基基团。W是CY或N。

  公开号：

  US20140371068A1

文献信息

• [EN] SUBSTITUTED PYRIMIDINES AND TRIAZINES AS HERBICIDES<br/>[FR] PYRIMIDINES ET TRIAZINES SUBSTITUÉES UTILISÉES EN TANT QU'HERBICIDES
  申请人：FMC CORP

  公开号：WO2021183980A1

  公开（公告）日：2021-09-16

  Disclosed are compounds of Formula I, stereoisomers, TV-oxides, and salts thereof, wherein; A is selected from A-2, A-2, A-3, A-4, A-5, A-6, A-7, A-8, A-9 and A-10 and A, A-l, A-2, A-3, A-4, A-5, A-6, A-7, A-8, A-9, A-10, R1 through R20b, W, X and Y are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula I and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  公开的是Formula I的化合物，立体异构体，TV-氧化物及其盐，其中；A从A-2，A-2，A-3，A-4，A-5，A-6，A-7，A-8，A-9和A-10中选择，A，A-l，A-2，A-3，A-4，A-5，A-6，A-7，A-8，A-9，A-10，R1到R20b，W，X和Y如披露中定义。还公开了含有Formula I化合物的组合物以及用于控制不受欢迎植被的方法，包括将不受欢迎的植被或其环境与本发明的化合物或组合物的有效量接触。
• [EN] PYRROLIDINONES AS HERBICIDES<br/>[FR] PYRROLIDINONES SERVANT D'HERBICIDES
  申请人：DU PONT

  公开号：WO2015084796A1

  公开（公告）日：2015-06-11

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof;. whereinRl,R2,R3,R4, R5, R6, Ql, Q2,yl, and Y2are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  公开了Formula 1的化合物，包括所有立体异构体、N-氧化物和盐；其中R1、R2、R3、R4、R5、R6、Q1、Q2、y1和y2如披露中定义。还公开了含有Formula 1化合物的组合物以及用于控制不受欢迎植被的方法，包括将不受欢迎的植被或其环境与本发明的化合物或组合物的有效量接触。
• PYRROLIDINONES HERBICIDES
  申请人：FMC CORPORATION

  公开号：US20200367494A1

  公开（公告）日：2020-11-26

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof: wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , Q 1 , Q 2 , Y 1 , and Y 2 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  揭示了Formula 1的化合物，包括所有立体异构体、N-氧化物和盐：其中R1、R2、R3、R4、R5、R6、Q1、Q2、Y1和Y2如披露中所定义。还披露了含有Formula 1化合物的组合物以及控制不良植被的方法，包括将不良植被或其环境与本发明的化合物或组合物的有效量接触。
• [EN] SUBSTITUTED CYCLIC AMIDES AND THEIR USE AS HERBICIDES<br/>[FR] AMIDES CYCLIQUES SUBSTITUÉS ET LEUR UTILISATION EN TANT QU'HERBICIDES
  申请人：DU PONT

  公开号：WO2016196593A1

  公开（公告）日：2016-12-08

  Disclosed are compounds of Formula 1, N-oxides of the compounds and salts of the compounds and N-oxides: wherein R1, R2, R3, R4, R5, R6, Q1, Q2, J, YI and Y2 are as defined in the disclosure. Also disclosed are compositions containing the compounds, N-oxides and salts, and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of such a compound, N-oxide, salt or composition.

  本公开了Formula 1的化合物，该化合物的N-氧化物和盐以及化合物和N-氧化物的盐：其中R1、R2、R3、R4、R5、R6、Q1、Q2、J、Y1和Y2如披露中所定义。还公开了含有这些化合物、N-氧化物和盐的组合物，以及用于控制不受欢迎的植被的方法，包括将不受欢迎的植被或其环境与这种化合物、N-氧化物、盐或组合物的有效量接触。
• [EN] NITRONE HERBICIDES<br/>[FR] HERBICIDES À BASE DE NITRONE
  申请人：FMC CORP

  公开号：WO2018118384A1

  公开（公告）日：2018-06-28

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, wherein R1, R2, R3, R4, R5, R6, J2, Q1, Q2, T and Y are as defined in the disclosure. Also disclosed are compositions containing the compounds, N-oxides and salts, and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound, N-oxide, salt or composition.

  本公开了化合物的结构，包括所有立体异构体、N-氧化物和盐，其中R1、R2、R3、R4、R5、R6、J2、Q1、Q2、T和Y如披露中所定义。还公开了含有这些化合物、N-氧化物和盐的组合物，以及用于控制不受欢迎的植被的方法，包括将不受欢迎的植被或其环境与一定量的化合物、N-氧化物、盐或组合物接触。