2,11,20,29-tetrakis(phenylmethyl)-4,13,22,31,37,38,39,40-octaoxapentacyclo[32.2.1.1(7,10).1(16,19).1(25,28)]tetraconta-1(36),7,9,16,18,25,27,34-octaene-3,12,21,30-tetrone | 1185763-11-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 2,11,20,29-tetrakis(phenylmethyl)-4,13,22,31,37,38,39,40-octaoxapentacyclo[32.2.1.1(7,10).1(16,19).1(25,28)]tetraconta-1(36),7,9,16,18,25,27,34-octaene-3,12,21,30-tetrone
• CAS: 1185763-11-4
• 化学式: C₆₀H₅₆O₁₂
• 分子量: 969.097
• InChiKey: QICMAZBSIYOTQE-UHFFFAOYSA-N

物化性质

• 密度：
  1.195±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为产物：
  描述：

  2-(5-(2-hydroxyethyl)furan-2-yl)-3-phenylpropanoic acid 在 4-二甲氨基吡啶 、 potassium carbonate 、 2,6-二氯苯甲酰氯 作用下， 以 二氯甲烷 为溶剂， 以3.5%的产率得到2,11-bis(phenylmethyl)-4,13,19,20-tetraoxatricyclo[14.2.1.1(7,10)]icosa-1(18),7,9,16-tetraene-3,12-dione
  参考文献：
  名称：

  Macrocyclisation of 2-(5-(2-hydroxyethyl)furan-2-yl)acetic acid model compounds of nonactic acid

  摘要：

  The macrocyclisation of hydroxyethylfuranyl acetic acid and of dehydrogenated model compounds of nonactic acid was investigated to develop a facile synthesis of nonactin analogues. By applying the Yamagushi macrocyclisation to our omega-hydroxyacids, we were able to isolate a mixture of di-, tri-, tetra- and pentameric macrocycles.

  DOI：

  10.1007/s00706-008-0031-4